Selective herbicides based on substituted arylsulfonylaminocarbonyl triazolinones and safeners

ABSTRACT

The invention relates to novel selective herbicidal compositions comprising an active compound combination consisting of substituted arylsulphonylaminocarbonyl-triazolinones and/or salts thereof and at least one compound which improves crop plant compatibility from the following group of compounds of the general formula (II),  
                 
in which n, m, X, Y and Z are as defined in the disclosure, it being possible to use the compositions with particularly good results for the selective control of weeds in various crops of useful plants. The invention further relates to the use of these compositions for controlling undesirable vegetation.

The invention relates to novel selective herbicidal active compound combinations comprising substituted arylsulphonylaminocarbonyl-triazolinones and/or salts thereof and at least one compound which improves crop plant compatibility, which combinations can be used with particularly good results for the selective control of weeds in various crops of useful plants.

Substituted arylsulphonylaminocarbonyl-triazolinones are already known as effective herbicides (cf. EP-A-341489, EP-A-422469, EP-A-425948, EP-A-431291, EP-A-507171, EP-A-534266, WO-A-96/11188, WO-A-96/27590, WO-A-96/27591, WO-A-97/03056). However, the activity of these compounds and/or their compatibility with crop plants are not under all conditions entirely satisfactory.

Also known are combinations of substituted arylsulphonylaminocarbonyl-triazolinones and other herbicidally active compounds to obtain a synergistic effect (cf. WO-A-98/12923). Combinations of substituted arylsulphonylaminocarbonyl-triazolinones and safeners, too, are already known (cf. DE-A-19940859, DE-A-19940860, U.S. Pat. No. 6,162,762). However, in these combination products, too, the use properties are not under all conditions entirely satisfactory. Furthermore, combinations of substituted arylsulphonylaminocarbonyl-triazolinones and further herbicidally active compounds, if appropriate with the additional use of safeners, also form part of the subject-matter of an earlier, but not prior published patent application (cf. DE-A-10031825 dated 30.06.2000).

Surprisingly, it has now been found that certain substituted arylsulphonylaminocarbonyl-triazolinones, when used together with the crop-plant-compatibility-improving compounds (safeners/antidotes) described below, prevent damage to the crop plants extremely well and can be used particularly advantageously as broad-spectrum combination preparations for the selective control of weeds in crops of useful plants, such as, for example, in cereals, maize and rice.

The invention provides selective herbicidal compositions, characterized by an effective amount of an active compound combination comprising

-   (a) one or more substituted arylsulphonylaminocarbonyl-triazolinones     of the formula (I) -    in which -   R¹ represents hydrogen, hydroxyl, amino, C₂-C₆-alkylideneamino,     represents in each case optionally cyano-, halogen- or     C₁-C₄-alkoxy-substituted alkyl, alkenyl, alkynyl, alkoxy,     alkenyloxy, alkylamino or dialkylamino having in each case up to 6     carbon atoms, represents in each case optionally cyano-, halogen- or     C₁-C₄-alkyl-substituted cycloalkyl, cycloalkylalkyl or     cycloalkylamino having in each case 3 to 6 carbon atoms in the     cycloalkyl group and, if appropriate, 1 to 4 carbon atoms in the     alkyl moiety, or represents in each case optionally cyano-, nitro-,     halogen-, C₁-C₄-alkyl-, C₁-C₄-haloalkyl-, C₁-C₄-alkoxy- or     C₁-C₄-haloalkoxy-substituted phenyl or phenyl-C₁-C₄-alkyl, -   R² represents hydrogen, hydroxyl, mercapto, amino, cyano, halogen,     represents in each case optionally cyano-, halogen- or     C₁-C₄-alkoxy-substituted alkyl, alkoxy, alkylthio, alkylamino,     dialkylamino, alkenyl, alkynyl, alkenyloxy, alkynyloxy, alkenylthio,     alkynylthio, alkenylamino or alkynylamino having in each case up to     6 carbon atoms, represents in each case optionally cyano-, halogen-     or C₁-C₄-alkyl-substituted cycloalkyl, cycloalkyloxy,     cycloalkylthio, cycloalkylamino, cycloalkylalkyl, cycloalkylalkoxy,     cycloalkylalkylthio or cycloalkylalkylamino having in each case 3 to     6 carbon atoms in the cycloalkyl group and, if appropriate, 1 to 4     carbon atoms in the alkyl moiety, or represents in each case     optionally cyano-, nitro-, halogen-, C₁-C₄-alkyl-, C₁-C₄-haloalkyl-,     C₁-C₄-alkoxy- or C₁-C₄-haloalkoxy-substituted phenyl, phenoxy,     phenylthio, phenylamino or phenyl-C₁-C₄-alkyl, -   R³ represents nitro, cyano, halogen, represents in each case     optionally cyano-, halogen- or C₁-C₄-alkoxy-substituted alkyl,     alkylcarbonyl, alkoxy, alkoxycarbonyl, alkylthio, alkylsulphinyl,     alkylsulphonyl, alkylamino, alkenyl, alkenyloxy, alkenylthio,     alkenylamino, alkynyl, alkynyloxy, alkynylthio having in each case     up to 6 carbon atoms, represents in each case optionally cyano-,     halogen- or C₁-C₄-alkyl-substituted cycloalkyl, cycloalkyloxy,     cycloalkylthio, cycloalkylamino having in each case 3 to 6 carbon     atoms in the cycloalkyl groups, or represents in each case     optionally cyano-, nitro-, halogen-, C₁-C₄-alkyl-, C₁-C₄-haloalkyl-,     C₁-C₄-alkoxy- or C₁-C₄-haloalkoxy-substituted phenyl, phenoxy,     phenylthio, phenylsulphinyl, phenylsulphonyl or phenylamino, and -   R⁴ represents hydrogen, nitro, cyano, halogen, represents in each     case optionally cyano-, halogen- or C₁-C₄-alkoxy-substituted alkyl,     alkylcarbonyl, alkoxy, alkoxycarbonyl, alkylthio, alkylsulphinyl,     alkylsulphonyl, alkylamino, alkenyl, alkenyloxy, alkenylthio,     alkenylamino, alkynyl, alkynyloxy or alkynylthio having in each case     up to 6 carbon atoms, represents in each case optionally cyano-,     halogen- or C₁-C₄-alkyl-substituted cycloalkyl, cycloalkyloxy,     cycloalkylthio, cycloalkylamino having in each case 3 to 6 carbon     atoms in the cycloalkyl groups, or represents in each case     optionally cyano-, nitro-, halogen-, C₁-C₄-alkyl-, C₁-C₄-haloalkyl-,     C₁-C₄-alkoxy- or C₁-C₄-haloalkoxy-substituted phenyl, phenoxy,     phenylthio, phenylsulphinyl, phenylsulphonyl or phenylamino,     including all possible tautomeric forms of the compounds of the     general formula (I) and salts formed by compounds of the general     formula (I) and basic compounds     (“active compounds of group 1”)     and -   (b) at least one compound which improves crop plant compatibility,     from the group of compounds of the general formula (II) below -    in which     -   m represents the numbers 0 to 5,     -   n represents the numbers 0 to 4,     -   X represents nitro, cyano, carboxyl, carbamoyl, formyl,         sulfamoyl, hydroxyl, amino, halogen, or represents in each case         optionally cyano-, halogen- or C₁-C₄-alkoxy-substituted alkyl,         alkoxy, alkoxycarbonyl, alkylthio, alkylsulphinyl,         alkylsulphonyl, alkylamino, alkylaminocarbonyl having in each         case 1 to 6 carbon atoms in the alkyl groups, or represents         dialkylamino, dialkylaminocarbonyl or dialkylaminosulphonyl         having in each case 1 to 6 carbon atoms in the alkyl groups,     -   Y represents nitro, cyano, carboxyl, carbamoyl, formyl,         sulfamoyl, hydroxyl, amino, halogen, or represents in each case         optionally cyano-, halogen- or C₁-C₄-alkoxy-substituted alkyl or         alkoxy having in each case 1 to 6 carbon atoms, and     -   Z represents one of the groupings below     -    in which         -   R⁵ represents hydrogen, represents optionally cyano-,             halogen- or C₁-C₄-alkoxy-substituted alkyl having 1 to 6             carbon atoms, represents in each case optionally             halogen-substituted alkenyl or alkynyl having in each case 3             to 6 carbon atoms, or represents in each case optionally             halogen- or C₁-C₄-alkyl-substituted cycloalkyl or             cycloalkylalkyl having in each case 3 to 6 carbon atoms in             the cycloalkyl group and, if appropriate, 1 to 4 carbon             atoms in the alkyl moiety,         -   R⁶ represents hydrogen, represents in each case optionally             cyano-, halogen-, C₁-C₄-alkoxy- or             C₁-C₄-alkylthio-substituted alkyl, alkoxy or alkylthio             having in each case 1 to 6 carbon atoms, represents in each             case optionally halogen-substituted alkenyl, alkenyloxy,             alkenylthio, alkynyl, alkynyloxy or alkynylthio having in             each case up to 6 carbon atoms, represents in each case             optionally halogen- or C₁-C₄-alkyl-substituted cycloalkyl or             cycloalkylalkyl having in each case 3 to 6 carbon atoms in             the cycloalkyl group and, if appropriate, 1 to 4 carbon             atoms in the alkyl moiety, represents in each case             optionally nitro-, cyano-, halogen-, C₁-C₄-alkyl-,             C₁-C₄-haloalkyl-, C₁-C₄-alkoxy- or             C₁-C₄-haloalkoxy-substituted aryl, aryloxy, arylthio,             arylalkyl, arylalkoxy or arylalkylthio having in each case 6             or 10 carbon atoms in the aryl group and, if appropriate, 1             to 4 carbon atoms in the alkyl moiety, or represents in each             case optionally nitro-, cyano-, halogen-, C₁-C₄-alkyl-,             C₁-C₄-haloalkyl-, C₁-C₄-alkoxy- or             C₁-C₄-haloalkoxy-substituted heterocyclyl, heterocyclyloxy,             heterocyclylthio, heterocyclylalkyl, heterocyclylalkoxy or             heterocyclylalkylthio having in each case up to 10 carbon             atoms, 1 to 4 nitrogen atoms and/or 1 or 2 oxygen or sulphur             atoms in the heterocyclyl group and, if appropriate, 1 to 4             carbon atoms in the alkyl moiety, and         -   R⁷ represents hydrogen, represents optionally cyano-,             halogen- or C₁-C₄-alkoxy-substituted alkyl having 1 to 6             carbon atoms, represents alkoxy having 1 to 6 carbon atoms,             represents in each case optionally halogen-substituted             alkenyl or alkynyl having in each case 3 to 6 carbon atoms,             represents alkenyloxy having 3 to 6 carbon atoms, represents             in each case optionally halogen- or C₁-C₄-alkyl-substituted             cycloalkyl or cycloalkylalkyl having 3 to 6 carbon atoms in             the cycloalkyl group and, if appropriate, 1 to 4 carbon             atoms in the alkyl moiety, or represents in each case             optionally nitro-, cyano-, halogen-, C₁-C₄-alkyl-,             C₁-C₄-haloalkyl-, C₁-C₄-alkoxy- or             C₁-C₄-haloalkoxy-substituted aryl or arylalkyl having in             each case 6 or 10 carbon atoms in the aryl group and, if             appropriate, 1 to 4 carbon atoms in the alkyl moiety, or             together with R⁵ represents in each case optionally             C₁-C₄-alkyl-substituted alkanediyl having 2 to 6 carbon             atoms or oxaalkanediyl having 2 to 5 carbon atoms             (“active compounds of group 2”).

In the definitions, the hydrocarbon chains, such as in alkyl or alkanediyl, are in each case straight-chain or branched—including in combination with heteroatoms, such as in alkoxy.

Preferred meanings of the groups listed above in connection with the general formula (I) are defined below.

-   R¹ preferably represents hydrogen, amino, propylideneamino,     butylideneamino, represents in each case optionally cyano-,     fluorine-, chlorine-, methoxy- or ethoxy-substituted methyl, ethyl,     n- or i-propyl, n-, i-, s- or t-butyl, ethenyl, propenyl, butenyl,     ethynyl, propynyl, butynyl, methoxy, ethoxy, n- or i-propoxy, n-,     i-, s- or t-butoxy, propenyloxy, butenyloxy, methylamino,     ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino,     dimethylamino or diethylamino, represents in each case optionally     cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or     i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl,     cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl,     cyclohexylmethyl, cyclopropylamino, cyclobutylamino,     cyclopentylamino or cyclohexylamino, or represents in each case     optionally cyano-, nitro-, fluorine-, chlorine-, bromine-, methyl-,     ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-, trifluoromethyl-,     methoxy-, ethoxy-, difluoromethoxy- or trifluoromethoxy-substituted     phenyl or benzyl. -   R² preferably represents hydrogen, hydroxyl, mercapto, amino, cyano,     fluorine, chlorine, bromine, represents in each case optionally     cyano-, fluorine-, chlorine-, methoxy- or ethoxy-substituted methyl,     ethyl, n- or i-propyl, n-, i-, s- or t-butyl, methoxy, ethoxy, n- or     i-propoxy, n-, i-, s- or t-butoxy, methylthio, ethylthio, n- or     i-propylthio, n-, i-, s- or t-butylthio, methylamino, ethylamino, n-     or i-propylamino, n-, i-, s- or t-butylamino, dimethylamino,     diethylamino, ethenyl, propenyl, butenyl, ethynyl, propynyl,     butynyl, propenyloxy, butenyloxy, propynyloxy, butynyloxy,     propenylthio, butenylthio, propynylthio, butynylthio, propenylamino,     butenylamino, propynylamino or butynylamino, represents in each case     optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-,     n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl,     cyclohexyl, cyclopropyloxy, cyclobutyloxy, cyclopentyloxy,     cyclohexyloxy, cyclopropylthio, cyclobutylthio, cyclopentylthio,     cyclohexylthio, cyclopropylamino, cyclobutylamino, cyclopentylamino,     cyclohexylamino, cyclopropylmethyl, cyclobutylmethyl,     cyclopentylmethyl, cyclohexylmethyl, cyclopropylmethoxy,     cyclobutylmethoxy, cyclopentylmethoxy, cyclohexylmethoxy,     cyclopropylmethylthio, cyclobutylmethylthio, cyclopentylmethylthio,     cyclohexylmethylthio, cyclopropylmethylamino, cyclobutylmethylamino,     cyclopentylmethylamino or cyclohexylmethylamino, or represents in     each case optionally cyano-, nitro-, fluorine-, chlorine-, bromine-,     methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-,     trifluoromethyl-, methoxy-, ethoxy-, difluoromethoxy- or     trifluoromethoxy-substituted phenyl, phenoxy, phenylthio,     phenylamino or benzyl. -   R³ preferably represents nitro, cyano, fluorine, chlorine, bromine,     represents in each case optionally cyano-, fluorine-, chlorine-,     methoxy- or ethoxy-substituted methyl, ethyl, n- or i-propyl, n-,     i-, s- or t-butyl, acetyl, propionyl, n- or i-butyroyl, methoxy,     ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, methoxycarbonyl,     ethoxycarbonyl, n- or i-propoxycarbonyl, methylthio, ethylthio, n-     or i-propylthio, n-, i-, s- or t-butylthio, methylsulphinyl,     ethylsulphinyl, n- or i-propylsulphinyl, methylsulphonyl,     ethylsulphonyl, n- or i-propylsulphonyl, methylamino, ethylamino, n-     or i-propylamino, n-, i-, s- or t-butylamino, ethenyl, propenyl,     butenyl, propenyloxy, butenyloxy, propenylthio, butenylthio,     propenylamino, butenylamino, ethynyl, propynyl, butynyl,     propynyloxy, butynyloxy, propynylthio or butynylthio, represents in     each case optionally cyano-, fluorine-, chlorine-, bromine-,     methyl-, ethyl-, n- or i-propyl-substituted cyclopropyl, cyclobutyl,     cyclopentyl, cyclohexyl, cyclopropyloxy, cyclobutyloxy,     cyclopentyloxy, cyclohexyloxy, cyclopropylthio, cyclobutylthio,     cyclopentylthio, cyclohexylthio, cyclopropylamino, cyclobutylamino,     cyclopentylamino or cyclohexylamino, or represents in each case     optionally cyano-, nitro-, fluorine-, chlorine-, bromine-, methyl-,     ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-, trifluoromethyl-,     methoxy-, ethoxy-, n- or i-propoxy-, n-, i-, s- or t-butoxy-,     difluoromethoxy- or trifluoromethoxy-substituted phenyl, phenoxy,     phenylthio, phenylsulphinyl, phenylsulphonyl or phenylamino. -   R⁴ preferably represents hydrogen, nitro, cyano, fluorine, chlorine,     bromine, represents in each case optionally cyano-, fluorine-,     chlorine-, methoxy- or ethoxy-substituted methyl, ethyl, n- or     i-propyl, n-, i-, s- or t-butyl, acetyl, propionyl, n- or     i-butyroyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or     t-butoxy, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl,     methylthio, ethylthio, n- or i-propylthio, n-, i-, s- or     t-butylthio, methylsulphinyl, ethylsulphinyl, n- or     i-propylsulphinyl, methylsulphonyl, ethylsulphonyl, n- or     i-propylsulphonyl, methylamino, ethylamino, n- or i-propylamino, n-,     i-, s- or t-butylamino, ethenyl, propenyl, butenyl, propenyloxy,     butenyloxy, propenylthio, butenylthio, propenylamino, butenylamino,     ethynyl, propynyl, butynyl, propynyloxy, butynyloxy, propynylthio or     butynylthio, represents in each case optionally cyano-, fluorine-,     chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-substituted     cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropyloxy,     cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, cyclopropylthio,     cyclobutylthio, cyclopentylthio, cyclohexylthio, cyclopropylamino,     cyclobutylamino, cyclopentylamino or cyclohexylamino, or represents     in each case optionally cyano-, nitro-, fluorine-, chlorine-,     bromine-, methyl-, ethyl-, n- or i-propyl-, trifluoromethyl-,     methoxy-, ethoxy-, n- or i-propoxy-, n-, i-, s- or t-butoxy-,     difluoromethoxy- or trifluoromethoxy-substituted phenyl, phenoxy,     phenylthio, phenylsulphinyl, phenylsulphonyl or phenylamino. -   R¹ particularly preferably represents hydrogen, amino, represents in     each case optionally fluorine-, chlorine-, methoxy- or     ethoxy-substituted methyl, ethyl, ethenyl, propenyl, ethynyl,     propynyl, methoxy, ethoxy, n- or i-propoxy, methylamino or     ethylamino, represents dimethylamino, or represents optionally     fluorine-, chlorine- or methyl-substituted cyclopropyl. -   R² particularly preferably represents hydrogen, chlorine, bromine,     represents in each case optionally fluorine-, chlorine-, methoxy- or     ethoxy-substituted methyl, ethyl, n- or i-propyl, n-, i- or s-butyl,     methoxy, ethoxy, n- or i-propoxy, methylthio, ethylthio, n- or     i-propylthio, methylamino, ethylamino, n- or i-propylamino,     dimethylamino, diethylamino, ethenyl, propenyl, butenyl, ethynyl,     propynyl, butynyl, propenyloxy, butenyloxy, propynyloxy, butynyloxy,     propenylthio, butenylthio, propynylthio, butynylthio, propenylamino,     butenylamino, propynylamino or butynylamino, or represents in each     case optionally fluorine-, chlorine- or methyl-substituted     cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropyloxy,     cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, cyclopropylthio,     cyclobutylthio, cyclopentylthio, cyclohexylthio, cyclopropylamino,     cyclobutylamino, cyclopentylamino, cyclohexylamino,     cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl,     cyclohexylmethyl, cyclopropylmethoxy, cyclobutylmethoxy,     cyclopentylmethoxy, cyclohexylmethoxy, cyclopropylmethylthio,     cyclobutylmethylthio, cyclopentylmethylthio, cyclohexylmethylthio,     cyclopropylmethylamino, cyclobutylmethylamino,     cyclopentylmethylamino and cyclohexylmethylamino. -   R³ particularly preferably represents nitro, cyano, fluorine,     chlorine, bromine, represents in each case optionally fluorine-,     chlorine-, methoxy- or ethoxy-substituted methyl, ethyl, n- or     i-propyl, methoxy, ethoxy, n- or i-propoxy, methoxycarbonyl,     ethoxycarbonyl, n- or i-propoxycarbonyl, methylthio, ethylthio, n-     or i-propylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl or     ethylsulphonyl, represents in each case optionally fluorine-,     chlorine- or methyl-substituted cyclopropyl, cyclobutyl,     cyclopentyl, cyclohexyl, cyclopropyloxy, cyclobutyloxy,     cyclopentyloxy, cyclohexyloxy, cyclopropylthio, cyclobutylthio,     cyclopentylthio or cyclohexylthio, or represents in each case     optionally cyano-, nitro-, fluorine-, chlorine-, bromine-, methyl-,     ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl, trifluoromethyl-,     methoxy-, ethoxy-, n- or i-propoxy-, difluoromethoxy- or     trifluoromethoxy-substituted phenyl, phenoxy, phenylthio,     phenylsulphinyl or phenylsulphonyl. -   R⁴ particularly preferably represents hydrogen, nitro, cyano,     fluorine, chlorine, bromine, or represents in each case optionally     fluorine-, chlorine-, methoxy- or ethoxy-substituted methyl, ethyl,     n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, methoxycarbonyl,     ethoxycarbonyl, n- or i-propoxycarbonyl, methylthio, ethylthio, n-     or i-propylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl or     ethylsulphonyl.     -   R¹ very particularly preferably represents hydrogen, represents         in each case optionally fluorine-, chlorine-, methoxy- or         ethoxy-substituted methyl, ethyl, ethenyl, methoxy, ethoxy,         methylamino or ethylamino, represents dimethylamino, or         represents optionally fluorine-, chlorine- or methyl-substituted         cyclopropyl.     -   R² very particularly preferably represents hydrogen, chlorine,         bromine, represents in each case optionally fluorine-,         chlorine-, methoxy- or ethoxy-substituted methyl, ethyl, n- or         i-propyl, n-, i- or s-butyl, methoxy, ethoxy, n- or i-propoxy,         methylthio, ethylthio, n- or i-propylthio, methylamino,         ethylamino, n- or i-propylamino, dimethylamino, diethylamino,         ethenyl, propenyl, butenyl, ethynyl, propynyl, butynyl,         propenyloxy, butenyloxy, propynyloxy, butynyloxy, propenylthio,         butenylthio, propynylthio, butynylthio, or represents in each         case optionally fluorine-, chlorine- or methyl-substituted         cyclopropyl, cyclopropyloxy, cyclopropylthio, cyclopropylmethyl,         cyclopropylmethoxy or cyclopropylmethylthio.     -   R³ very particularly preferably represents nitro, cyano,         fluorine, chlorine, bromine, represents in each case optionally         fluorine-, chlorine-, methoxy- or ethoxy-substituted methyl,         ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy,         methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl,         methylthio, ethylthio, n- or i-propylthio, methylsulphinyl,         ethylsulphinyl, methylsulphonyl or ethylsulphonyl, or represents         in each case optionally cyano-, nitro-, fluorine-, chlorine-,         bromine-, methyl-, ethyl-, trifluoromethyl-, methoxy-, ethoxy-,         difluoromethoxy- or trifluoromethoxy-substituted phenyl or         phenoxy.     -   R⁴ very particularly preferably represents hydrogen, nitro,         cyano, fluorine, chlorine, bromine, or represents in each case         optionally fluorine-, chlorine-, methoxy- or ethoxy-substituted         methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy,         methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl,         methylthio, ethylthio, n- or i-propylthio, methylsulphinyl,         ethylsulphinyl, methylsulphonyl or ethylsulphonyl.

Instead of the pure active compounds of the formula (I), it is also possible to use salts of the compounds of the formula (I) with metals and/or with basic nitrogen compounds in the active compound combinations according to the invention.

Here, preference is given to salts of the compounds of the formula (I) with alkali metals, such as, for example, lithium, sodium, potassium, rubidium or caesium, in particular with sodium or potassium, with alkaline earth metals, such as, for example, magnesium, calcium or barium, in particular with calcium, or with earth metals, such as, for example, aluminium.

Preference is furthermore given to salts of the compounds of the formula (I) with ammonia, with C₁-C₆-alkyl-amines, such as, for example, with methylamine, ethylamine, n- or i-propylamine, n-, i-, s- or t-butylamine, n-, i-, s- or t-pentylamine, with di-(C₁-C₆-alkyl)-amines, such as, for example, dimethylamine, diethylamine, dipropylamine, diisopropylamine, dibutylamine, diisobutylamine, di-s-butylamine, dipentylamine, diisopentylamine, di-s-pentylamine and dihexylamine, with tri-(C₁-C₄-alkyl)-amines, such as, for example, trimethylamine, triethylamine, tripropylamine, tributylamine and N-ethyldiisopropylamine, with C₃-C₆-cycloalkylamines, such as, for example, cyclopentylamine or cyclohexylamine, with di-(C₃-C₆-cycloalkyl)-amines, such as, for example, dicyclopentylamine or dicyclohexylamine, with N-C₁-C₄-alkyl-C₃-C₆-cycloalkylamines, such as, for example, N-methylcyclopentylamine, N-ethylcyclopentylamine, N-methylcyclohexylamine or N-ethylcyclohexylamine, with N,N-di-(C₁-C₄-alkyl)-C₃-C₆-cycloalkyl-amines, such as, for example, N,N-dimethylcyclopentylamine, N,N-diethylcyclopentylamine, N,N-dimethylcyclohexylamine or N,N-diethyl-cyclohexylamine, with N-C₁-C₄-alkyl-di-(C₃-C₆-cycloalkyl)-amines, such as, for example, N-methyldicyclopentylamine, N-ethyldicyclopentylamine, N-methyldicyclohexylamine or N-ethyldicyclohexylamine, with phenyl-C₁-C₄-alkylamines, such as, for example, benzylamine, 1-phenylethylamine or 2-phenylethylamine, with N-C₁-C₄-alkyl-phenyl-C₁-C₄-alkyl-amines, such as, for example, N-methylbenzylamine or N-ethylbenzylamine, or N,N-di-(C₁-C₄-alkyl)-phenyl-C₁-C₄-alkyl-amines, such as, for example, N,N-dimethylbenzylamine or N,N-diethylbenzylamine, or with optionally fused and/or C₁-C₄-alkyl-substituted azines, such as, for example, pyridine, quinoline, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, 2,4-dimethylpyridine, 2,5-dimethylpyridine, 2,6-dimethylpyridine or 5-ethyl-2-methylpyridine.

Basic compounds which may be mentioned as being suitable for preparing the salts of the compounds of the formula (I) which can be used according to the invention are:

alkali metal or alkaline earth metal acetates, amides, carbonates, bicarbonates, hydrides, hydroxides or alkoxides, such as, for example, sodium acetate, potassium acetate or calcium acetate, lithium amide, sodium amide, potassium amide or calcium amide, sodium carbonate, potassium carbonate or calcium carbonate, sodium bicarbonate, potassium bicarbonate or calcium bicarbonate, lithium hydride, sodium hydride, potassium hydride or calcium hydride, lithium hydroxide, sodium hydroxide, potassium hydroxide or calcium hydroxide, sodium methoxide, ethoxide, n- or i-propoxide, n-, i-, s- or t-butoxide or potassium methoxide, ethoxide, n- or i-propoxide, n-, i-, s- or t-butoxide.

Examples of suitable mixing partners according to the invention for the compounds of the formula (I) to be used which may be mentioned are:

2-(2-chlorophenylsulphonylaminocarbonyl)-, 2-(2-bromophenylsulphonylaminocarbonyl)-, 2-(2-methylphenylsulphonylaminocarbonyl)-, 2-(2-ethylphenylsulphonylaminocarbonyl)-, 2-(2-n-propylphenylsulphonylaminocarbonyl)-, 2-(2-i-propylphenylsulphonylaminocarbonyl)-, 2-(2-trifluoromethyl-phenylsulphonylaminocarbonyl)-, 2-(2-methoxyphenylsulphonylaminocarbonyl)-, 2-(2-ethoxyphenylsulphonylaminocarbo-nyl)-, 2-(2-n-propoxyphenylsulphonylaminocarbonyl)-, 2-(2-i-propoxyphenylsulphonylaminocarbonyl)-, 2-(2-difluoromethoxyphenylsulphonylaminocarbonyl)-, 2-(2-trifluoromethoxyphenylsulphonylaminocarbonyl)-, 2-(2-methoxycarbonylphenylsulphonylaminocarbonyl)-, 2-(2-ethoxycarbonylphenylsulphonylaminocarbonyl)-, 2-(2-n-propoxycarbonylphenylsulphonylaminocarbonyl)-, 2-(2-i-propoxycarbonylphenylsulphonylaminocarbonyl)- and 2-(2-chloro-6-methylphenylsulphonylaminocarbonyl)-4-methyl-5-methoxy-2,4-dihydro-3H-1,2,4-triazol-3-one, -4-methyl-5-ethoxy-2,4-dihydro-3H-1 ,2,4-triazol-3-one, -4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazol-3-one, -4-methyl-5-i-propoxy-2,4-dihydro-3H-1,2,4-triazol-3-one, -4-methyl-5-trifluoroethoxy-2,4-dihydro-3H-1,2,4-triazol-3-one, -4-methyl-5-methylthio-2,4-dihydro-3H-1,2,4-triazol-3-one, -4-methyl-5-ethylthio-2,4-dihydro-3H-1,2,4-triazol-3-one, -4-methoxy-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one, -4-methoxy-5-ethyl-2,4-dihydro-3H-1,2,4-triazol-3-one, -4-methoxy-5-n-propyl-2,4-dihydro-3H-1,2,4-triazol-3-one, -4-cyclopropyl-5-methoxy-2,4-dihydro-3H-1,2,4-triazol-3-one, -4-cyclopropyl-5-ethoxy-2,4-dihydro-3H-1,2,4-triazol-3-one, -4-cyclopropyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazol-3-one, -4-cyclopropyl-5-i-propoxy-2,4-dihydro-3H-1,2,4-triazol-3-one and -4-cyclopropyl-5-trifluoroethoxy-2,4-dihydro-3H-1,2,4-triazol-3-one and the sodium and potassium salts of these compounds.

Particular emphasis as mixing components of the formula (I) is given to the compounds 2-(2-methoxycarbonylphenylsulphonylaminocarbonyl)-4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazol-3-one (I-1, propoxycarbazone) and 2-(2-trifluoromethoxyphenylsulphonylaminocarbonyl)-4-methyl-5-methoxy-2,4-dihydro-3H-1,2,4-triazol-3-one (I-2, flucarbazone) and their sodium salts—(I-1-Na salt, propoxycabazone-sodium, and I-2-Na salt, flucarbazone-sodium).

The compounds of the formula (I) are described in the patent applications or patents mentioned above.

Preferred meanings of the groups listed above in connection with the general formula (II) are defined below.

-   m preferably represents the number 0, 1, 2, 3 or 4. -   n preferably represents the number 0, 1, 2 or 3. -   X preferably represents nitro, cyano, carboxyl, carbamoyl, formyl,     sulfamoyl, hydroxy, amino, halogen, represents in each case     optionally cyano-, halogen-, methoxy-, ethoxy-, n- or     i-propoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or     t-butyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy,     methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, n-, i-, s-     or t-butoxycarbonyl, methylthio, ethylthio, n- or i-propylthio, n-,     i-, s- or t-butylthio, methylsulphinyl, ethylsulphinyl, n- or     i-propylsulphinyl, methylsulphonyl, ethylsulphonyl, methylamino,     ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino,     methylaminocarbonyl, ethylaminocarbonyl, n- or     i-propylaminocarbonyl, or represents dimethylamino, diethylamino,     dimethylaminocarbonyl or dimethylaminosulphonyl. -   Y preferably represents nitro, cyano, carboxyl, carbamoyl, formyl,     sulphamoyl, hydroxyl, amino, halogen, or represents in each case     optionally cyano-, halogen-, methoxy-, ethoxy-, n- or     i-propoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or     t-butyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy,     and -   Z represents preferably one of the groupings below -    in which     -   R⁵ preferably represents hydrogen, represents in each case         optionally cyano-, halogen-, methoxy-, ethoxy-, n- or         i-propoxy-, n-, i-, s- or t-butoxy-substituted methyl, ethyl, n-         or i-propyl, n-, i-, s- or t-butyl, n-, i-, s- or t-pentyl, or         neo-pentyl, represents in each case optionally         halogen-substituted propenyl, butenyl, pentenyl, propynyl,         butynyl or pentynyl, or represents in each case optionally         halogen-, methyl-, ethyl-, n- or i-propyl-substituted         cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl,         cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl or         cyclohexylmethyl,     -   R⁶ preferably represents hydrogen, represents in each case         optionally cyano-, halogen-, methoxy-, ethoxy-, n- or         i-propoxy-, n-, i-, s- or t-butoxy-, methylthio-, ethylthio-, n-         or i-propylthio-, n-, i-, s- or t-butylthio-substituted methyl,         ethyl, n- or i-propyl, n-, i-, s- or t-butyl, n-, i-, s- or         t-pentyl, or neo-pentyl, methoxy, ethoxy, n- or i-propoxy, n-,         i-, s- or t-butoxy, methylthio, ethylthio, n- or i-propylthio,         n-, i-, s- or t-butylthio, represents in each case optionally         halogen-substituted propenyl, butenyl, pentenyl, propenyloxy,         butenyloxy, pentenyloxy, propenylthio, butenylthio,         pentenylthio, propynyl, butynyl, pentynyl, propynyloxy,         butynyloxy, pentynyloxy, propynylthio, butynylthio or         pentynylthio, represents in each case optionally halogen-,         methyl-, ethyl-, n- or i-propyl-substituted cyclopropyl,         cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl,         cyclobutylmethyl, cyclopentylmethyl or cyclohexylmethyl,         represents in each case optionally nitro-, cyano-, halogen-,         methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-,         trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-,         difluoromethoxy- or trifluoromethoxy-substituted phenyl,         naphthyl, phenoxy, phenylthio, benzyl, phenylethyl,         phenylmethoxy, phenylethoxy or phenylmethylthio, or represents         in each case optionally nitro-, cyano-, halogen-, methyl-,         ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-,         trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-,         difluoromethoxy- or trifluoromethoxy-substituted heterocyclyl,         heterocyclyloxy, heterocyclylthio, heterocyclylmethyl,         heterocyclylmethoxy or heterocyclylmethylthio, where the         heterocyclyl group is preferably selected from the group         consisting of furyl, thienyl, pyrazolyl, pyridinyl, pyrimidinyl,     -   R⁷ preferably represents hydrogen, represents in each case         optionally cyano-, halogen-, methoxy-, ethoxy-, n- or         i-propoxy-, n-, i-, s- or t-butoxy-substituted methyl, ethyl, n-         or i-propyl, n-, i-, s- or t-butyl, n-, i-, s- or t-pentyl, or         neo-pentyl, represents methoxy, ethoxy, n- or i-propoxy, n-, i-,         s- or t-butoxy, represents in each case optionally         halogen-substituted propenyl, butenyl, pentenyl, propynyl,         butynyl or pentynyl, represents propenyloxy, butenyloxy or         pentenyloxy, represents in each case optionally halogen-,         methyl-, ethyl-, n- or i-propyl-substituted cyclopropyl,         cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl,         cyclobutylmethyl, cyclopentylmethyl or cyclohexylmethyl, or         represents in each case optionally nitro-, cyano-, halogen-,         methyl-, ethyl-, n- or i-propyl, n-, i-, s- or t-butyl-,         trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-,         difluoromethoxy- or trifluoromethoxy-substituted phenyl,         naphthyl, benzyl or phenylethyl, or together with R⁵ represents         in each case optionally methyl- or ethyl-substituted         butane-1,4-diyl (tetramethylene), 1-oxabutan-1,4-diyl,         pentane-1,5-diyl, 1-oxapentane-1,5-diyl or         3-oxapentane-1,5-diyl. -   m particularly preferably represents the number 1 or 2. -   n particularly preferably represents the number 0. -   X particularly preferably represents nitro, cyano, fluorine,     chlorine, bromine, represents in each case optionally fluorine-,     chlorine-, methoxy- or ethoxy-substituted methyl, ethyl, n- or     i-propyl, methoxy, ethoxy, n- or i-propoxy, methoxycarbonyl,     ethoxycarbonyl, n- or i-propoxycarbonyl, methylthio, ethylthio, n-     or i-propylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl,     ethylsulphonyl, methylamino, ethylamino, n- or i-propylamino,     methylaminocarbonyl, ethylaminocarbonyl, n- or     i-propylaminocarbonyl, or represents dimethylamino,     dimethylaminocarbonyl or dimethylaminosulphonyl. -   Z particularly preferably represents one of the groupings below -    in which     -   R⁵ particularly preferably represents hydrogen, represents in         each case optionally cyano-, fluorine-, chlorine-, methoxy-,         ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- or         i-propyl, n- or i-butyl, represents in each case optionally         fluorine- and/oder chlorine-substituted propenyl, butenyl,         propynyl or butynyl, or represents in each case optionally         fluorine-, chlorine-, methyl- or ethyl-substituted cyclopropyl,         cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl,         cyclobutylmethyl, cyclopentylmethyl or cyclohexylmethyl,     -   R⁶ particularly preferably represents hydrogen, represents in         each case optionally cyano-, fluorine-, chlorine-, bromine-,         methoxy-, ethoxy-, n- or i-propoxy-, methylthio-, ethylthio-, n-         or i-propylthio-substituted methyl, ethyl, n- or i-propyl, n-,         i-, s- or t-butyl, n-, i-, s- or t-pentyl, or neo-pentyl,         methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy,         methylthio, ethylthio, n- or i-propylthio, n-, i-, s- or         t-butylthio, represents in each case optionally fluorine-         and/oder chlorine-substituted propenyl, butenyl, pentenyl,         propenyloxy, butenyloxy, pentenyloxy, propenylthio, butenylthio,         pentenylthio, propynyl, butynyl, pentynyl, propynyloxy,         butynyloxy, pentynyloxy, propynylthio, butynylthio or         pentynylthio, represents in each case optionally fluorine-,         chlorine-, methyl- or ethyl-substituted cyclopropyl, cyclobutyl,         cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl,         cyclopentylmethyl or cyclohexylmethyl, represents in each case         optionally nitro-, cyano-, fluorine-, chlorine-, bromine-,         methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-,         trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-,         difluoromethoxy- or trifluoromethoxy-substituted phenyl,         phenoxy, phenylthio, benzyl, phenylethyl, phenylmethoxy,         phenylethoxy or phenylmethylthio, or represents in each case         optionally nitro-, cyano-, halogen-, methyl-, ethyl-, n- or         i-propyl-, n-, i-, s- or t-butyl-, trifluoromethyl-, methoxy-,         ethoxy-, n- or i-propoxy-, difluoromethoxy- or         trifluoromethoxy-substituted heterocyclyl, heterocyclyloxy,         heterocyclylthio, heterocyclylmethyl, heterocyclylmethoxy or         heterocyclylmethylthio, where the heterocyclyl group is         preferably selected from the group consisting of furyl, thienyl,         pyrazolyl, pyridinyl and pyrimidinyl, and     -   R⁷ particularly preferably represents hydrogen, represents in         each case optionally cyano-, fluorine-, chlorine-, methoxy-,         ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- or         i-propyl, n-, i-, s- or t-butyl, n-, i-, s- or t-pentyl, or         neo-pentyl, represents methoxy, ethoxy, n- or i-propoxy, n-, i-,         s- or t-butoxy, represents in each case optionally fluorine-         and/oder chlorine-substituted propenyl, butenyl, pentenyl,         propynyl, butynyl or pentynyl, represents propenyloxy,         butenyloxy or pentenyloxy, represents in each case optionally         fluorine-, chlorine-, methyl- or ethyl-substituted cyclopropyl,         cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl,         cyclobutylmethyl, cyclopentylmethyl or cyclohexylmethyl, or         represents in each case optionally nitro-, cyano-, fluorine-,         chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i-,         s- or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, n- or         i-propoxy-, difluoromethoxy- or trifluoromethoxy-substituted         phenyl, benzyl or phenylethyl, or together with R⁵ represents in         each case optionally methyl- or ethyl-substituted         butane-1,4-diyl (tetramethylene), 1-oxabutane-1,4-diyl,         pentane-1,5-diyl, 1-oxapentane-1,5-diyl or         3-oxapentane-1,5-diyl.

A very particularly preferred group of safeners to be used according to the invention are the compounds of the general formula (IIa)

in which

m, n, R , R , X and Y have the meanings given above as being preferred or as being particularly preferred.

Examples of the compounds of the formula (IIa) which are very particularly preferred as safeners to be used according to the invention are listed in Table 1 below. TABLE 1 Examples of compounds of the formula (IIa) (IIa)

(Position/s) (Position/s) Ex. No. R⁵ R⁶ X_(m) Y_(n) IIa-1 H H (2) OCH₃ — IIa-2 H CH₃ (2) OCH₃ — IIa-3 H CH₃ (2) OCH₃, (4) Cl — IIa-4 H CH₃ (2) OCH₃, (4) CH₃ — IIa-5 H CH₃ (2) OCH₃, (5) Cl — IIa-6 H CH₃ (2) OCH₃, (4) Cl — IIa-7 H CH₃ (2) OCH₃, (5) CH₃ — IIa-8 H CH₃ (2) CF₃ — IIa-9 H CH₃ (2) OCHF₂ — IIa-10 H CH₃ (2) OCF₃ — IIa-11 H CH₃ (2) Cl — IIa-12 H CH₃ (2) OC₂H₅ — IIa-13 H C₂H₅ (2) OCH₃ — IIa-14 H C₂H₅ (2) OCH₃, (4) Cl — IIa-15 H C₂H₅ (2) OCH₃, (4) CH₃ — IIa-16 H C₂H₅ (2) OCH₃, (5) Cl — IIa-17 H C₂H₅ (2) OCH₃, (4) Cl — IIa-18 H C₂H₅ (2) OCH₃, (5) CH₃ — IIa-19 H C₂H₅ (2) CF₃ — IIa-20 H C₂H₅ (2) OCHF₂ — IIa-21 H C₂H₅ (2) OCF₃ — IIa-22 H C₂H₅ (2) Cl — IIa-23 H C₂H₅ (2) OC₂H₅ — IIa-24 H C₃H₇-n (2) OCH₃ — IIa-25 H C₃H₇-n (2) OCH₃, (4) Cl — IIa-26 H C₃H₇-n (2) OCH₃, (4) CH₃ — IIa-27 H C₃H₇-n (2) OCH₃, (5) Cl — IIa-28 H C₃H₇-n (2) OCH₃, (4) Cl — IIa-29 H C₃H₇-n (2) OCH₃, (5) CH₃ — IIa-30 H C₃H₇-n (2) CF₃ — IIa-31 H C₃H₇-n (2) OCHF₂ — IIa-32 H C₃H₇-n (2) OCF₃ — IIa-33 H C₃H₇-n (2) Cl — IIa-34 H C₃H₇-n (2) OC₂H₅ — IIa-35 H C₃H₇-i (2) OCH₃ — IIa-36 H C₃H₇-i (2) OCH₃, (4) Cl — IIa-37 H C₃H₇-i (2) OCH₃, (4) CH₃ — IIa-38 H C₃H₇-i (2) OCH₃, (5) Cl — IIa-39 H C₃H₇-i (2) OCH₃, (4) Cl — IIa-40 H C₃H₇-i (2) OCH₃, (5) CH₃ — IIa-41 H C₃H₇-i (2) CF₃ — IIa-42 H C₃H₇-i (2) OCHF₂ — IIa-43 H C₃H₇-i (2) OCF₃ — IIa-44 H C₃H₇-i (2) Cl — IIa-45 H C₃H₇-i (2) OC₂H₅ — IIa-46 H

(2) OCH₃ — IIa-47 H

(2) OCH₃, (4) Cl — IIa-48 H

(2) OCH₃, (4) CH₃ — IIa-49 H

(2) OCH₃, (5) Cl — IIa-50 H

(2) OCH₃, (4) Cl — IIa-51 H

(2) OCH₃, (5) CH₃ — IIa-52 H

(2) CH₃ — IIa-53 H

(2) CF₃ — IIa-54 H

(2) OC₂H₅ — IIa-55 H

(2) Cl — IIa-56 H

(2) Cl, (5) Cl — IIa-57 H C₄H₉-i (2) OCH₃ — IIa-58 H C₄H₉-i (2) OCH₃, (4) Cl — IIa-59 H C₄H₉-i (2) OCH₃, (4) CH₃ — IIa-60 H C₄H₉-i (2) OCH₃, (5) Cl — IIa-61 H C₄H₉-i (2) OCH₃, (4) Cl — IIa-62 H C₄H₉-i (2) OCH₃, (5) CH₃ — IIa-63 H C₄H₉-i (2) CF₃ — IIa-64 H C₄H₉-i (2) OCHF₂ — IIa-65 H C₄H₉-i (2) OCF₃ — IIa-66 H C₄H₉-i (2) Cl — IIa-67 H C₄H₉-i (2) OC₂H₅ — IIa-68 H C₄H₉-s (2) OCH₃ — IIa-69 H C₄H₉-s (2) OCH₃, (4) Cl — IIa-70 H C₄H₉-s (2) OCH₃, (4) CH₃ — IIa-71 H C₄H₉-s (2) OCH₃, (5) Cl — IIa-72 H C₄H₉-s (2) OCH₃, (4) Cl — IIa-73 H C₄H₉-s (2) OCH₃, (5) CH₃ — IIa-74 H C₄H₉-s (2) CF₃ — IIa-75 H C₄H₉-s (2) OCHF₂ — IIa-76 H C₄H₉-s (2) OCF₃ — IIa-77 H C₄H₉-s (2) Cl — IIa-78 H C₄H₉-s (2) OC₂H₅ — IIa-79 H C₄H₉-t (2) OCH₃ — IIa-80 H C₄H₉-t (2) OCH₃, (4) Cl — IIa-81 H C₄H₉-t (2) OCH₃, (4) CH₃ — IIa-82 H C₄H₉-t (2) OCH₃, (5) Cl — IIa-83 H C₄H₉-t (2) OCH₃, (4) Cl — IIa-84 H C₄H₉-t (2) OCH₃, (5) CH₃ — IIa-85 H C₄H₉-t (2) CF₃ — IIa-86 H C₄H₉-t (2) OCHF₂ — IIa-87 H C₄H₉-t (2) OCF₃ — IIa-88 H C₄H₉-t (2) Cl — IIa-89 H C₄H₉-t (2) OC₂H₅ — IIa-90 H C₄H₉-t (2) OCH₃ — IIa-91 H

(2) OCH₃, (4) Cl — IIa-92 H

(2) OCH₃, (4) CH₃ — IIa-93 H

(2) OCH₃, (5) Cl — IIa-94 H

(2) OCH₃, (4) Cl — IIa-95 H

(2) OCH₃, (5) CH₃ — IIa-96 H

(2) CF₃ — IIa-97 H

(2) OCHF₂ — IIa-98 H

(2) OCF₃ — IIa-99 H

(2) Cl — IIa-100 H

(2) OC₂H₅ — IIa-101 H CH₂OCH₃ (2) OCH₃ — IIa-102 H CH₂OCH₃ (2) OCH₃, (4) Cl — IIa-103 H CH₂OCH₃ (2) OCH₃, (4) CH₃ — IIa-104 H CH₂OCH₃ (2) OCH₃, (5) Cl — IIa-105 H CH₂OCH₃ (2) OCH₃, (4) Cl — IIa-106 H CH₂OCH₃ (2) OCH₃, (5) CH₃ — IIa-107 H CH₂OCH₃ (2) CF₃ — IIa-108 H CH₂OCH₃ (2) OCHF₂ — IIa-109 H CH₂OCH₃ (2) OCF₃ — IIa-110 H CH₂OCH₃ (2) Cl — IIa-111 H CH₂OCH₃ (2) OC₂H₅ — IIa-112 H CH₂OCH₃ (2) CH₃ — IIa-113 H CH₂OCH₃ (2) Cl, (4) Cl — IIa-114 H CH₂OCH₃ (2) Cl, (5) Cl — IIa-115 H CH₂OCH₃ (2) OCH₃, (5) OCH₃ — IIa-116 H CH₂OCH₃ (2) CH₃, (4) CH₃ — IIa-117 H CH₂OCH₃ (2) CH₃, (5) CH₃ — IIa-118 H CH₂Cl (2) OCH₃ — IIa-119 H CH₂Cl (2) OCH₃, (4) Cl — IIa-120 H CH₂Cl (2) OCH₃, (4) CH₃ — IIa-121 H CH₂Cl (2) OCH₃, (5) Cl — IIa-122 H CH₂Cl (2) OCH₃, (4) Cl — IIa-123 H CH₂Cl (2) OCH₃, (5) CH₃ — IIa-124 H CH₂Cl (2) CF₃ — IIa-125 H CH₂Cl (2) OCHF₂ — IIa-126 H CH₂Cl (2) OCF₃ — IIa-127 H CH₂Cl (2) Cl — IIa-128 H CH₂Cl (2) OC₂H₅ — IIa-129 H CH₂Cl (2) CH₃ — IIa-130 H CH₂Cl (2) Cl, (4) Cl — IIa-131 H CH₂Cl (2) Cl, (5) Cl — IIa-132 H CH₂Cl (2) OCH₃, (5) OCH₃ — IIa-133 H CH₂Cl (2) CH₃, (4) CH₃ — IIa-134 H CH₂Cl (2) CH₃, (5) CH₃ — IIa-135 H CHCl₂ (2) OCH₃ — IIa-136 H CHCl₂ (2) OCH₃, (4) Cl — IIa-137 H CHCl₂ (2) OCH₃, (4) CH₃ — IIa-138 H CHCl₂ (2) OCH₃, (5) Cl — IIa-139 H CHCl₂ (2) OCH₃, (4) Cl — IIa-140 H CHCl₂ (2) OCH₃, (5) CH₃ — IIa-141 H CHCl₂ (2) CF₃ — IIa-142 H CHCl₂ (2) OCHF₂ — IIa-143 H CHCl₂ (2) OCF₃ — IIa-144 H CHCl₂ (2) Cl — IIa-145 H CHCl₂ (2) OC₂H₅ — IIa-146 H CHCl₂ (2) CH₃ — IIa-147 H CHCl₂ (2) Cl, (4) Cl — IIa-148 H CHCl₂ (2) Cl, (5) Cl — IIa-149 H CHCl₂ (2) OCH₃, (5) OCH₃ — IIa-150 H CHCl₂ (2) CH₃, (4) CH₃ — IIa-151 H CHCl₂ (2) CH₃, (5) CH₃ — IIa-152 H CH₂CH₂Cl (2) OCH₃ — IIa-153 H CH₂CH₂Cl (2) OCH₃, (4) Cl — IIa-154 H CH₂CH₂Cl (2) OCH₃, (4) CH₃ — IIa-155 H CH₂CH₂Cl (2) OCH₃, (5) Cl — IIa-156 H CH₂CH₂Cl (2) OCH₃, (4) Cl — IIa-157 H CH₂CH₂Cl (2) OCH₃, (5) CH₃ — IIa-158 H CH₂CH₂Cl (2) CF₃ — IIa-159 H CH₂CH₂Cl (2) OCHF₂ — IIa-160 H CH₂CH₂Cl (2) OCF₃ — IIa-161 H CH₂CH₂Cl (2) Cl — IIa-162 H CH₂CH₂Cl (2) OC₂H₅ — IIa-163 H CH₂CH₂Cl (2) CH₃ — IIa-164 H CH₂CH₂Cl (2) Cl, (4) Cl — IIa-165 H CH₂CH₂Cl (2) Cl, (5) Cl — IIa-166 H CH₂CH₂Cl (2) OCH₃, (5) OCH₃ — IIa-167 H CH₂CH₂Cl (2) CH₃, (4) CH₃ — IIa-168 H CH₂CH₂Cl (2) CH₃, (5) CH₃ — IIa-169 H

(2) OCH₃ — IIa-170 H

(2) OCH₃, (4) Cl — IIa-171 H

(2) OCH₃, (4) CH₃ — IIa-172 H

(2) OCH₃, (5) Cl — IIa-173 H

(2) OCH₃, (4) Cl — IIa-174 H

(2) OCH₃, (5) CH₃ — IIa-175 H

(2) CF₃ — IIa-176 H

(2) OCHF₂ — IIa-177 H

(2) OCF₃ — IIa-178 H

(2) Cl — IIa-179 H

(2) OC₂H₅ — IIa-180 H

(2) CH₃ — IIa-181 H

(2) Cl, (4) Cl — IIa-182 H

(2) Cl, (5) Cl — IIa-183 H

(2) OCH₃, (5) OCH₃ — IIa-184 H

(2) CH₃, (4) CH₃ — IIa-185 H

(2) CH₃, (5) CH₃ — IIa-186 H OCH₃ (2) OCH₃ — IIa-187 H OCH₃ (2) OCH₃, (4) Cl — IIa-188 H OCH₃ (2) OCH₃, (4) CH₃ — IIa-189 H OCH₃ (2) OCH₃, (5) Cl — IIa-190 H OCH₃ (2) OCH₃, (4) Cl — IIa-191 H OCH₃ (2) OCH₃, (5) CH₃ — IIa-192 H OCH₃ (2) CF₃ — IIa-193 H OCH₃ (2) OCHF₂ — IIa-194 H OCH₃ (2) OCF₃ — IIa-195 H OCH₃ (2) Cl — IIa-196 H OCH₃ (2) OC₂H₅ — IIa-197 H OCH₃ (2) CH₃ — IIa-198 H OCH₃ (2) Cl, (4) Cl — IIa-199 H OCH₃ (2) Cl, (5) Cl — IIa-200 H OCH₃ (2) OCH₃, (5) OCH₃ — IIa-201 H OCH₃ (2) CH₃, (4) CH₃ — IIa-202 H OCH₃ (2) CH₃, (5) CH₃ — IIa-203 H OC₂H₅ (2) OCH₃ — IIa-204 H OC₂H₅ (2) OCH₃, (4) Cl — IIa-205 H OC₂H₅ (2) OCH₃, (4) CH₃ — IIa-206 H OC₂H₅ (2) OCH₃, (5) Cl — IIa-207 H OC₂H₅ (2) OCH₃, (4) Cl — IIa-208 H OC₂H₅ (2) OCH₃, (5) CH₃ — IIa-209 H OC₂H₅ (2) CF₃ — IIa-210 H OC₂H₅ (2) OCHF₂ — IIa-211 H OC₂H₅ (2) OCF₃ — IIa-212 H OC₂H₅ (2) Cl — IIa-213 H OC₂H₅ (2) OC₂H₅ — IIa-214 H OC₂H₅ (2) CH₃ — IIa-215 H OC₂H₅ (2) Cl, (4) Cl — IIa-216 H OC₂H₅ (2) Cl, (5) Cl — IIa-217 H OC₂H₅ (2) OCH₃, (5) OCH₃ — IIa-218 H OC₂H₅ (2) CH₃, (4) CH₃ — IIa-219 H OC₂H₅ (2) CH₃, (5) CH₃ — IIa-220 H OC₃H₇-n (2) OCH₃ — IIa-221 H OC₃H₇-n (2) OCH₃, (4) Cl — IIa-222 H OC₃H₇-n (2) OCH₃, (4) CH₃ — IIa-223 H OC₃H₇-n (2) OCH₃, (5) Cl — IIa-224 H OC₃H₇-n (2) OCH₃, (4) Cl — IIa-225 H OC₃H₇-n (2) OCH₃, (5) CH₃ — IIa-226 H OC₃H₇-n (2) CF₃ — IIa-227 H OC₃H₇-n (2) OCHF₂ — IIa-228 H OC₃H₇-n (2) OCF₃ — IIa-229 H OC₃H₇-n (2) Cl — IIa-230 H OC₃H₇-n (2) OC₂H₅ — IIa-231 H OC₃H₇-n (2) CH₃ — IIa-232 H OC₃H₇-n (2) Cl, (4) Cl — IIa-233 H OC₃H₇-n (2) Cl, (5) Cl — IIa-234 H OC₃H₇-n (2) OCH₃, (5) OCH₃ — IIa-235 H OC₃H₇-n (2) CH₃, (4) CH₃ — IIa-236 H OC₃H₇-n (2) CH₃, (5) CH₃ — IIa-237 H OC₃H₇-i (2) OCH₃ — IIa-238 H OC₃H₇-i (2) OCH₃, (4) Cl — IIa-239 H OC₃H₇-i (2) OCH₃, (4) CH₃ — IIa-240 H OC₃H₇-i (2) OCH₃, (5) Cl — IIa-241 H OC₃H₇-i (2) OCH₃, (4) Cl — IIa-242 H OC₃H₇-i (2) OCH₃, (5) CH₃ — IIa-243 H OC₃H₇-i (2) CF₃ — IIa-244 H OC₃H₇-i (2) OCHF₂ — IIa-245 H OC₃H₇-i (2) OCF₃ — IIa-246 H OC₃H₇-i (2) Cl — IIa-247 H OC₃H₇-i (2) OC₂H₅ — IIa-248 H OC₃H₇-i (2) CH₃ — IIa-249 H OC₃H₇-i (2) Cl, (4) Cl — IIa-250 H OC₃H₇-i (2) Cl, (5) Cl — IIa-251 H OC₃H₇-i (2) OCH₃, (5) OCH₃ — IIa-252 H OC₃H₇-i (2) CH₃, (4) CH₃ — IIa-253 H OC₃H₇-i (2) CH₃, (5) CH₃ — IIa-254 H OC₆H₅ (2) OCH₃ — IIa-255 H OC₆H₅ (2) OCH₃, (4) Cl — IIa-256 H OC₆H₅ (2) OCH₃, (4) CH₃ — IIa-257 H OC₆H₅ (2) OCH₃, (5) Cl — IIa-258 H OC₆H₅ (2) OCH₃, (4) Cl — IIa-259 H OC₆H₅ (2) OCH₃, (5) CH₃ — IIa-260 H OC₆H₅ (2) CF₃ — IIa-261 H OC₆H₅ (2) OCHF₂ — IIa-262 H OC₆H₅ (2) OCF₃ — IIa-263 H OC₆H₅ (2) Cl — IIa-264 H OC₆H₅ (2) OC₂H₅ — IIa-265 H OC₆H₅ (2) CH₃ — IIa-266 H OC₆H₅ (2) Cl, (4) Cl — IIa-267 H OC₆H₅ (2) Cl, (5) Cl — IIa-268 H OC₆H₅ (2) OCH₃, (5) OCH₃ — IIa-269 H OC₆H₅ (2) CH₃, (4) CH₃ — IIa-270 H OC₆H₅ (2) CH₃, (5) CH₃ — IIa-271 H SCH₃ (2) OCH₃ — IIa-272 H SCH₃ (2) OCH₃, (4) Cl — IIa-273 H SCH₃ (2) OCH₃, (4) CH₃ — IIa-274 H SCH₃ (2) OCH₃, (5) Cl — IIa-275 H SCH₃ (2) OCH₃, (4) Cl — IIa-276 H SCH₃ (2) OCH₃, (5) CH₃ — IIa-277 H SCH₃ (2) CF₃ — IIa-278 H SCH₃ (2) OCHF₂ — IIa-279 H SCH₃ (2) OCF₃ — IIa-280 H SCH₃ (2) Cl — IIa-281 H SCH₃ (2) OC₂H₅ — IIa-282 H SCH₃ (2) CH₃ — IIa-283 H SCH₃ (2) Cl, (4) Cl — IIa-284 H SCH₃ (2) Cl, (5) Cl — IIa-285 H SCH₃ (2) OCH₃, (5) OCH₃ — IIa-286 H SCH₃ (2) CH₃, (4) CH₃ — IIa-287 H SCH₃ (2) CH₃, (5) CH₃ — IIa-288 H SC₂H₅ (2) OCH₃ — IIa-289 H SC₂H₅ (2) OCH₃, (4) Cl — IIa-290 H SC₂H₅ (2) OCH₃, (4) CH₃ — IIa-291 H SC₂H₅ (2) OCH₃, (5) Cl — IIa-292 H SC₂H₅ (2) OCH₃, (4) Cl — IIa-293 H SC₂H₅ (2) OCH₃, (5) CH₃ — IIa-294 H SC₂H₅ (2) CF₃ — IIa-295 H SC₂H₅ (2) OCHF₂ — IIa-296 H SC₂H₅ (2) OCF₃ — IIa-297 H SC₂H₅ (2) Cl IIa-298 H SC₂H₅ (2) OC₂H₅ IIa-299 H SC₂H₅ (2) CH₃ IIa-300 H SC₂H₅ (2) Cl, (4) Cl IIa-301 H SC₂H₅ (2) Cl, (5) Cl IIa-302 H SC₂H₅ (2) OCH₃, (5) OCH₃ IIa-303 H SC₂H₅ (2) CH₃, (4) CH₃ IIa-304 H SC₂H₅ (2) CH₃, (5) CH₃

A further very particularly preferred group of safeners to be used according to the invention are the compounds of the general formula (IIb)

in which

m, n, R⁵, R⁷, X and Y have the meanings given above as being preferred or as being particularly preferred.

Examples of the compounds of the formula (IIb) which are very particularly preferred as safeners to be used according to the invention are listed in Table 2 below. TABLE 2 Examples of compounds of the formula (IIb) (IIb)

(Position/s) (Position/s) Ex. No. R⁵ R⁷ X_(m) Y_(n) IIb-1 H H (2) OCH₃ — IIb-2 H CH₃ (2) OCH₃ — IIb-3 H CH₃ (2) OCH₃ — IIb-4 H CH₃ (2) OCH₃, (4) Cl — IIb-5 H CH₃ (2) OCH₃, (4) CH₃ — IIb-6 H CH₃ (2) OCH₃, (5) Cl — IIb-7 H CH₃ (2) OCH₃, (4) Cl — IIb-8 H CH₃ (2) OCH₃, (5) CH₃ — IIb-9 H CH₃ (2) CF₃ — IIb-10 H CH₃ (2) OCHF₂ — IIb-11 H CH₃ (2) OCF₃ — IIb-12 H CH₃ (2) Cl — IIb-13 H CH₃ (2) OC₂H₅ — IIb-14 H C₂H₅ (2) OCH₃ — IIb-15 H C₂H₅ (2) OCH₃, (4) Cl — IIb-16 H C₂H₅ (2) OCH₃, (4) CH₃ — IIb-17 H C₂H₅ (2) OCH₃, (5) Cl — IIb-18 H C₂H₅ (2) OCH₃, (4) Cl — IIb-19 H C₂H₅ (2) OCH₃, (5) CH₃ — IIb-20 H C₂H₅ (2) CF₃ — IIb-21 H C₂H₅ (2) OCHF₂ — IIb-22 H C₂H₅ (2) OCF₃ — IIb-23 H C₂H₅ (2) Cl — IIb-24 H C₂H₅ (2) OC₂H₅ — IIb-25 H C₂H₅ (2) CH₃ — IIb-26 H C₂H₅ (2) Cl, (4) Cl — IIb-27 H C₂H₅ (2) Cl, (5) Cl — IIb-28 H C₂H₅ (2) OCH₃, (5) OCH₃ — IIb-29 H C₂H₅ (2) CH₃, (4) CH₃ — IIb-30 H C₂H₅ (2) CH₃, (5) CH₃ — IIb-31 H C₃H₇-n (2) OCH₃ — IIb-32 H C₃H₇-n (2) OCH₃, (4) Cl — IIb-33 H C₃H₇-n (2) OCH₃, (4) CH₃ — IIb-34 H C₃H₇-n (2) OCH₃, (5) Cl — IIb-35 H C₃H₇-n (2) OCH₃, (4) Cl — IIb-36 H C₃H₇-n (2) OCH₃, (5) CH₃ — IIb-37 H C₃H₇-n (2) CF₃ — IIb-38 H C₃H₇-n (2) OCHF₂ — IIb-39 H C₃H₇-n (2) OCF₃ — IIb-40 H C₃H₇-n (2) Cl — IIb-41 H C₃H₇-n (2) OC₂H₅ — IIb-42 H C₃H₇-n (2) CH₃ — IIb-43 H C₃H₇-n (2) Cl, (4) Cl — IIb-44 H C₃H₇-n (2) Cl, (5) Cl — IIb-45 H C₃H₇-n (2) OCH₃, (5) OCH₃ — IIb-46 H C₃H₇-n (2) CH₃, (4) CH₃ — IIb-47 H C₃H₇-n (2) CH₃, (5) CH₃ — IIb-48 H C₃H₇-i (2) OCH₃ — IIb-49 H C₃H₇-i (2) OCH₃, (4) Cl — IIb-50 H C₃H₇-i (2) OCH₃, (4) CH₃ — IIb-51 H C₃H₇-i (2) OCH₃, (5) Cl — IIb-52 H C₃H₇-i (2) OCH₃, (4) Cl — IIb-53 H C₃H₇-i (2) OCH₃, (5) CH₃ — llb-54 H C₃H₇-i (2) CF₃ — IIb-55 H C₃H₇-i (2) OCHF₂ — IIb-56 H C₃H₇-i (2) OCF₃ — IIb-57 H C₃H₇-i (2) Cl — IIb-58 H C₃H₇-i (2) OC₂H₅ — IIb-59 H C₃H₇-i (2) CH₃ — IIb-60 H C₃H₇-i (2) Cl, (4) Cl — IIb-61 H C₃H₇-i (2) Cl, (5) Cl — IIb-62 H C₃H₇-i (2) OCH₃, (5) OCH₃ — IIb-63 H C₃H₇-i (2) CH₃, (4) CH₃ — IIb-64 H C₃H₇-i (2) CH₃, (5) CH₃ — IIb-65 H CH₂CH═CH₂ (2) OCH₃ — IIb-66 H CH₂CH═CH₂ (2) OCH₃, (4) Cl — IIb-67 H CH₂CH═CH₂ (2) OCH₃, (4) CH₃ — IIb-68 H CH₂CH═CH₂ (2) OCH₃, (5) Cl — IIb-69 H CH₂CH═CH₂ (2) OCH₃, (4) Cl — IIb-70 H CH₂CH═CH₂ (2) OCH₃, (5) CH₃ — IIb-71 H CH₂CH═CH₂ (2) CF₃ — IIb-72 H CH₂CH═CH₂ (2) OCHF₂ — IIb-73 H CH₂CH═CH₂ (2) OCF₃ — IIb-74 H CH₂CH═CH₂ (2) Cl — IIb-75 H CH₂CH═CH₂ (2) OC₂H₅ — IIb-76 H CH₂CH═CH₂ (2) CH₃ — IIb-77 H CH₂CH═CH₂ (2) Cl, (4) Cl — IIb-78 H CH₂CH═CH₂ (2) Cl, (5) Cl — IIb-79 H CH₂CH═CH₂ (2) OCH₃, (5) OCH₃ — IIb-80 H CH₂CH═CH₂ (2) CH₃, (4) CH₃ — IIb-81 H CH₂CH═CH₂ (2) CH₃, (5) CH₃ — IIb-82 H

(2) OCH₃ — IIb-83 H

(2) OCH₃, (4) Cl — IIb-84 H

(2) OCH₃, (4) CH₃ — IIb-85 H

(2) OCH₃, (5) Cl — IIb-86 H

(2) OCH₃, (4) Cl — IIb-87 H

(2) OCH₃, (5) CH₃ — IIb-88 H

(2) CF₃ — IIb-89 H

(2) OCHF₂ — IIb-90 H

(2) OCF₃ — IIb-91 H

(2) Cl — IIb-92 H

(2) OC₂H₅ — IIb-93 H

(2) CH₃ — IIb-94 H

(2) Cl, (4) Cl — IIb-95 H

(2) Cl, (5) Cl — IIb-96 H

(2) OCH₃, (5) OCH₃ — IIb-97 H

(2) CH₃, (4) CH₃ — IIb-98 H

(2) CH₃, (5) CH₃ — IIb-99 H C₄H₉-n (2) OCH₃ — IIb-100 H C₄H₉-n (2) OCH₃, (4) Cl — IIb-101 H C₄H₉-n (2) OCH₃, (4) CH₃ — IIb-102 H C₄H₉-n (2) OCH₃, (5) Cl — IIb-103 H C₄H₉-n (2) OCH₃, (4) Cl — IIb-104 H C₄H₉-n (2) OCH₃, (5) CH₃ — IIb-105 H C₄H₉-n (2) CF₃ — IIb-106 H C₄H₉-n (2) OCHF₂ — IIb-107 H C₄H₉-n (2) OCF₃ — IIb-108 H C₄H₉-n (2) Cl — IIb-109 H C₄H₉-n (2) OC₂H₅ — IIb-110 H C₄H₉-n (2) CH₃ — IIb-111 H C₄H₉-n (2) Cl, (4) Cl — IIb-112 H C₄H₉-n (2) Cl, (5) Cl — IIb-113 H C₄H₉-n (2) OCH₃, (5) OCH₃ — IIb-114 H C₄H₉-n (2) CH₃, (4) CH₃ — IIb-115 H C₄H₉-n (2) CH₃, (5) CH₃ — IIb-116 H C₄H₉-i (2) OCH₃ — IIb-117 H C₄H₉-i (2) OCH₃, (4) Cl — IIb-118 H C₄H₉-i (2) OCH₃, (4) CH₃ — IIb-119 H C₄H₉-i (2) OCH₃, (5) Cl — IIb-120 H C₄H₉-i (2) OCH₃, (4) Cl — IIb-121 H C₄H₉-i (2) OCH₃, (5) CH₃ — IIb-122 H C₄H₉-i (2) CF₃ — IIb-123 H C₄H₉-i (2) OCHF₂ — IIb-124 H C₄H₉-i (2) OCF₃ — IIb-125 H C₄H₉-i (2) Cl — IIb-126 H C₄H₉-i (2) OC₂H₅ — IIb-127 H C₄H₉-i (2) CH₃ — IIb-128 H C₄H₉-i (2) Cl, (4) Cl — IIb-129 H C₄H₉-i (2) Cl, (5) Cl — IIb-130 H C₄H₉-i (2) OCH₃, (5) OCH₃ — IIb-131 H C₄H₉-i (2) CH₃, (4) CH₃ — IIb-132 H C₄H₉-i (2) CH₃, (5) CH₃ — IIb-133 H C₄H₉-s (2) OCH₃ — IIb-134 H C₄H₉-s (2) OCH₃, (4) Cl — IIb-135 H C₄H₉-s (2) OCH₃, (4) CH₃ — IIb-136 H C₄H₉-s (2) OCH₃, (5) Cl — IIb-137 H C₄H₉-s (2) OCH₃, (4) Cl — IIb-138 H C₄H₉-s (2) OCH₃, (5) CH₃ — IIb-139 H C₄H₉-s (2) CF₃ — IIb-140 H C₄H₉-s (2) OCHF₂ — IIb-141 H C₄H₉-s (2) OCF₃ — IIb-142 H C₄H₉-s (2) Cl — IIb-143 H C₄H₉-s (2) OC₂H₅ — IIb-144 H C₄H₉-s (2) CH₃ — IIb-145 H C₄H₉-s (2) Cl, (4) Cl — IIb-146 H C₄H₉-s (2) Cl, (5) Cl — IIb-147 H C₄H₉-s (2) OCH₃, (5) OCH₃ — IIb-148 H C₄H₉-s (2) CH₃, (4) CH₃ — IIb-149 H C₄H₉-s (2) CH₃, (5) CH₃ — IIb-150 H CH₂CH₂OCH₃ (2) OCH₃ — IIb-151 H CH₂CH₂OCH₃ (2) OCH₃, (4) Cl — IIb-152 H CH₂CH₂OCH₃ (2) OCH₃, (4) CH₃ — IIb-153 H CH₂CH₂OCH₃ (2) OCH₃, (5) Cl — IIb-154 H CH₂CH₂OCH₃ (2) OCH₃, (4) Cl — IIb-155 H CH₂CH₂OCH₃ (2) OCH₃, (5) CH₃ — IIb-156 H CH₂CH₂OCH₃ (2) CF₃ — IIb-157 H CH₂CH₂OCH₃ (2) OCHF₂ — IIb-158 H CH₂CH₂OCH₃ (2) OCF₃ — IIb-159 H CH₂CH₂OCH₃ (2) Cl — IIb-160 H CH₂CH₂OCH₃ (2) OC₂H5 — IIb-161 H CH₂CH₂OCH₃ (2) CH₃ — IIb-162 H CH₂CH₂OCH₃ (2) Cl, (4) Cl — IIb-163 H CH₂CH₂OCH₃ (2) Cl, (5) Cl — IIb-164 H CH₂CH₂OCH₃ (2) OCH₃, (5) OCH₃ — IIb-165 H CH₂CH₂OCH₃ (2) CH₃, (4) CH₃ — IIb-166 H CH₂CH₂OCH₃ (2) CH₃, (5) CH₃ — IIb-167 H

(2) OCH₃ — IIb-168 H

(2) OCH₃, (4) Cl — IIb-169 H

(2) OCH₃, (4) CH₃ — IIb-170 H

(2) OCH₃, (5) Cl — IIb-171 H

(2) OCH₃, (4) Cl — IIb-172 H

(2) OCH₃, (5) CH₃ — IIb-173 H

(2) CF₃ — IIb-174 H

(2) OCHF₂ — IIb-175 H

(2) OCF₃ — IIb-176 H

(2) Cl — IIb-177 H

(2) OC₂H₅ — IIb-178 H

(2) CH₃ — IIb-179 H

(2) Cl, (4) Cl — IIb-180 H

(2) Cl, (5) Cl — IIb-181 H

(2) OCH₃, (5) OCH₃ — IIb-182 H

(2) CH₃, (4) CH₃ — IIb-183 H

(2) CH₃, (5) CH₃ — IIb-184 H CH₂CH₂OC₂H₅ (2) OCH₃ — IIb-185 H CH₂CH₂OC₂H₅ (2) OCH_(3,) (4) Cl — IIb-186 H CH₂CH₂OC₂H₅ (2) OCH_(3,) (4) CH₃ — IIb-187 H CH₂CH₂OC₂H₅ (2) OCH_(3,) (5) Cl — IIb-188 H CH₂CH₂OC₂H₅ (2) OCH_(3,) (4) Cl — IIb-189 H CH₂CH₂OC₂H₅ (2) OCH_(3,) (5) CH₃ — IIb-190 H CH₂CH₂OC₂H₅ (2) CF₃ — IIb-191 H CH₂CH₂OC₂H₅ (2) OCHF₂ — IIb-192 H CH₂CH₂OC₂H₅ (2) OCF₃ — IIb-193 H CH₂CH₂OC₂H₅ (2) Cl — IIb-194 H CH₂CH₂OC₂H₅ (2) OC₂H₅ — IIb-195 H CH₂CH₂OC₂H₅ (2) CH₃ — IIb-196 H CH₂CH₂OC₂H₅ (2) Cl, (4) Cl — IIb-197 H CH₂CH₂OC₂H₅ (2) Cl, (5) Cl — IIb-198 H CH₂CH₂OC₂H₅ (2) OCH₃, (5) OCH₃ — IIb-199 H CH₂CH₂OC₂H₅ (2) CH₃, (4) CH₃ — IIb-200 H CH₂CH₂OC₂H₅ (2) CH₃, (5) CH₃ — IIb-201 CH₃ CH₃ (2) OCH₃ — IIb-202 CH₃ CH₃ (2) OCH₃, (4) Cl — IIb-203 CH₃ CH₃ (2) OCH₃, (4) CH₃ — IIb-204 CH₃ CH₃ (2) OCH₃, (5) Cl — IIb-205 CH₃ CH₃ (2) OCH₃, (4) Cl — IIb-206 CH₃ CH₃ (2) OCH₃, (5) CH₃ — IIb-207 CH₃ CH₃ (2) CF₃ — IIb-208 CH₃ CH₃ (2) OCHF₂ — IIb-209 CH₃ CH₃ (2) OCF₃ — IIb-210 CH₃ CH₃ (2) Cl — IIb-211 CH₃ CH₃ (2) OC₂H₅ — IIb-212 CH₃ CH₃ (2) CH₃ — IIb-213 CH₃ CH₃ (2) Cl, (4) Cl — IIb-214 CH₃ CH₃ (2) Cl, (5) Cl — IIb-215 CH₃ CH₃ (2) OCH₃, (5) OCH₃ — IIb-216 CH₃ CH₃ (2) CH₃, (4) CH₃ — IIb-217 CH₃ CH₃ (2) CH₃, (5) CH₃ — IIb-218 C₂H₅ C₂H₅ (2) OCH₃ — IIb-219 C₂H₅ C₂H₅ (2) OCH₃, (4) Cl — IIb-220 C₂H₅ C₂H₅ (2) OCH₃, (4) CH₃ — IIb-221 C₂H₅ C₂H₅ (2) OCH₃, (5) Cl — IIb-222 C₂H₅ C₂H₅ (2) OCH₃, (4) Cl — IIb-223 C₂H₅ C₂H₅ (2) OCH₃, (5) CH₃ — IIb-224 C₂H₅ C₂H₅ (2) CF₃ — IIb-225 C₂H₅ C₂H₅ (2) OCHF₂ — IIb-226 C₂H₅ C₂H₅ (2) OCF₃ — IIb-227 C₂H₅ C₂H₅ (2) Cl — IIb-228 C₂H₅ C₂H₅ (2) OC₂H₅ — IIb-229 C₂H₅ C₂H₅ (2) CH₃ — IIb-230 C₂H₅ C₂H₅ (2) Cl, (4) Cl — IIb-231 C₂H₅ C₂H₅ (2) Cl, (5) Cl — IIb-232 C₂H₅ C₂H₅ (2) OCH₃, (5) OCH₃ — IIb-233 C₂H₅ C₂H₅ (2) CH₃, (4) CH₃ — IIb-234 C₂H₅ C₂H₅ (2) CH₃, (5) CH₃

The compounds of the general formula (II) are known and/or can be prepared by processes known per se (cf. WO-A-97/45016/U.S. Pat. No. B1-6,235,680; WO-A-99/66795/U.S. Pat. No. B1-6,251,827; WO-A-99/16744).

Examples of the selective herbicidal combinations according to the invention of in each case one active compound of the general formula (I) and in each case one safener of the general formula (II) which are given particular emphasis are:

Active compound (I-1)—propoxycarbazone—in combination with the safeners listed in Table 1, in particular (IIa-13) to (IIa-56), (IIa-101) to (IIa-168) and (IIa-186) to (IIa-304), in particular IIa-101.

Active compound (I-1-Na salt)—propoxycarbazone-sodium—in combination with the safeners listed in Table 1, in particular (IIa-13) to (IIa-56), (IIa-101) to (IIa-168) and (IIa-186) to (IIa-304), in particular IIa-101.

Active compound (I-2)—flucarbazone—in combination with the safeners listed in Table 1, in particular (IIa-13) to (IIa-56), (IIa-101) to (IIa-168) and (IIa-186) to (IIa-304), in particular IIa-101.

Active compound (I-2-Na salt)—flucarbazone-sodium—in combination with the safeners listed in Table 1, in particular (IIa-13) to (IIa-56), (IIa-101) to (IIa-168) and (IIa-186) to (IIa-304), in particular IIa-101.

Active compound (I-1)—propoxycarbazone—in combination with the safeners listed in Table 2, in particular (IIb-14) to (IIb-98), (IIb-150) to (IIb-234).

Active compound (I-1-Na salt)—propoxycarbazone-sodium—in combination with the safeners listed in Table 2, in particular (IIb-14) to (IIb-98), (IIb-150) to (IIb-234).

Active compound (I-2)—flucarbazone—in combination with the safeners listed in Table 2, in particular (IIb-14) to (IIb-98), (IIb-150) to (IIb-234).

Active compound (I-2-Na salt)—flucarbazone-sodium—in combination with the safeners listed in Table 2, in particular (IIb-14) to (IIb-98), (IIb-150) to (IIb-234).

Surprisingly, it has now been found that the active compound combinations defined above of substituted arylsulphonylaminocarbonyl-triazolinones of the general formula (I) and safeners (antidotes) of the general formula (II), whilst being highly compatible with crop plants, have a particularly high herbicidal activity and can be used in various crops, in particular cereals (especially barley and wheat), but also maize and rice, for the selective control of weeds.

Here, it has to be considered to be surprising that, from a large number of known safeners or antidotes which are capable of antagonizing the damaging effect of a herbicide on the crop plants, it is in particular the compounds of the formula (II) listed above which neutralize the damaging effect of substituted arylsulphonylaminocarbonyl-triazolinones on the crop plants virtually completely without negatively affecting the herbicidal activity with respect to the weeds.

Emphasis is given here to the particularly advantageous effect of the particularly and most preferred combination partners from the general formula (II), in particular in respect of sparing cereal plants, such as, for example, wheat, barley and rye, but also maize and rice, as crop plants.

The active compound combinations according to the invention can be used, for example, in connection with the following plants:

Dicotyledonous weeds of the genera: Sinapis, Lepidium, Galium, Stellaria, Matricaria, Anthemis, Galinsoga, Chenopodium, Urtica, Senecio, Amaranthus, Portulaca, Xanthium, Convolvulus, Ipomoea, Polygonum, Sesbania, Ambrosia, Cirsium, Carduus, Sonchus, Solanum, Rorippa, Rotala, Lindernia, Lamium, Veronica, Abutilon, Emex, Datura, Viola, Galeopsis, Papaver, Centaurea, Trifolium, Ranunculus, Taraxacum.

Dicotyledonous crops of the genera: Gossypium, Glycine, Beta, Daucus, Phaseolus, Pisum, Solanum, Linum, Ipomoea, Vicia, Nicotiana, Lycopersicon, Arachis, Brassica, Lactuca, Cucumis, Cuburbita, Helianthus.

Monocotyledonous weeds of the genera: Echinochloa, Setaria, Panicum, Digitaria, Phleum, Poa, Festuca, Eleusine, Brachiaria, Lolium, Bromus, Avena, Cyperus, Sorghum, Agropyron, Cynodon, Monochoria, Fimbristylis, Sagittaria, Eleocharis, Scirpus, Paspalum, Ischaemum, Sphenoclea, Dactyloctenium, Agrostis, Alopecurus, Apera.

Monocotyledonous crops of the genera: Oryza, Zea, Triticum, Hordeum, Avena, Secale, Sorghum, Panicum, Saccharum, Ananas, Asparagus, Allium.

However, the use of the active compound combinations according to the invention is in no way restricted to these genera, but also extends in the same manner to other plants. According to the invention, crop plants are all plants and plant varieties including transgenic plants and plant varieties, where on transgenic plants and plant varieties it is also possible for synergistic effects to occur.

The advantageous effect of the crop plant compatibility of the active compound combinations according to the invention is particularly highly pronounced at certain concentration ratios. However, the weight ratios of the active compounds in the active compound concentrations can be varied within relatively wide ranges. In general, 0.001 to 1000 parts by weight, preferably 0.01 to 100 parts by weight, and particularly preferably 0.1 to 10 parts by weight of one of the compounds which improve crop plant compatibility mentioned under (b) above (antidotes/safeners) are present per part by weight of active compound of the formula (I) or its salts.

The active compounds or active compound combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusting agents, pastes, soluble powders, granules, suspoemulsion concentrates, natural and synthetic materials impregnated with active compound, and very fine capsules in polymeric substances.

These formulations are produced in a known manner, for example by mixing the active compounds with extenders, that is liquid solvents and/or solid carriers, optionally with the use of surfactants, that is emulsifiers and/or dispersants and/or foam-formers.

If the extender used is water, it is also possible to use, for example, organic solvents as auxiliary solvents. Suitable liquid solvents are essentially: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols, such as butanol or glycol, and also their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulfoxide, and also water.

Suitable solid carriers are:

for example ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, ground synthetic minerals, such as finely divided silica, alumina and silicates, suitable solid carriers for granules are: for example crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite and dolomite, and also synthetic granules of inorganic and organic meals, and granules of organic material such as sawdust, coconut shells, maize cobs and tobacco stalks; suitable emulsifiers and/or foam-formers are: for example non-ionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolyzates; suitable dispersants are: for example lignosulfite waste liquors and methylcellulose.

Tackifiers such as carboxymethylcellulose and natural and synthetic polymers in the form of powders, granules or latices, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, and also natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids, can be used in the formulations. Other possible additives are mineral and vegetable oils.

It is possible to use colorants such as inorganic pigments, for example iron oxide, titanium oxide and Prussian Blue, and organic dyestuffs, such as alizarin dyestuffs, azo dyestuffs and metal phthalocyanine dyestuffs, and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

The formulations generally comprise from 0.1 to 95 percent by weight of active compounds including the safeners, preferably between 0.5 and 90%.

The active compound combinations according to the invention are generally used in the form of finished formulations. However, the active compounds contained in the active compound combinations can also be mixed in individual formulations when used, i.e. in the form of tank mixes.

The novel active compound combinations, as such or in their formulations, can furthermore be used as a mixture with other known herbicides, finished formulations or tank mixes again being possible. A mixture with other known active compounds, such as fungicides, insecticides, acaricides, nematicides, bird repellents, growth factors, plant nutrients and agents which improve soil structure, is also possible. For certain intended uses, in particular in the post-emergence method, it may furthermore be advantageous to include, as further additives in the formulations, mineral or vegetable oils which are tolerated by plants (for example the commercial preparation “Rako Binol”), or ammonium salts such as, for example, ammonium sulphate or ammonium thiocyanate.

The novel active compound combinations can be used as such, in the form of their formulations or the use forms prepared therefrom by further dilution, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granules. They are used in the customary manner, for example by washing, spraying, atomizing, dusting or scattering.

The amounts of the active compound combinations according to the invention applied can be varied within a certain range; they depend, inter alia, on the weather and on soil factors. In general, the application rates are between 0.005 and 5 kg per ha, preferably between 0.01 and 2 kg per ha, particularly preferably between 0.05 and 1.0 kg per ha.

The active compound combinations according to the invention can be applied before and after emergence of the plants, that is to say by the pre-emergence and post-emergence method.

USE EXAMPLES

The active compound (flucarbazone-sodium and propoxycarbazone-sodium were each used as WG 70) or safener components are in each case dissolved in a few ml (generally 2-3 ml) of solvent (generally acetone or N,N-dimethyl-formamide), and the solutions are combined and then—if appropriate after addition of an emulsifier—diluted with water to the desired concentration. In general, an aqueous spray liquor was prepared using 0.5% of the additive Renex-36.

Example A

Post-Emergence Test

The test plants are grown under controlled conditions (temperature, light, atmospheric humidity) in a greenhouse. The test plants are sprayed when they have reached a height of 5-15 cm. The concentration of the spray liquor is chosen such that the particular amounts of active compound desired are applied in 500 l of water/ha.

After spraying, the pots with the test plants are kept in a greenhouse chamber under controlled conditions (temperature, light, atmospheric humidity) until the test has ended. About three weeks after the application, the degree of damage to the crop plants is rated in % damage in comparison to the development of the untreated control.

The figures denote:

-   -   0%=no damage (like untreated control)     -   100%=total destruction/damage

Active compounds, application rates, test plants and results are shown in the tables below, the terms being used in the tables being as defined below:

a.i.=active ingredient=active compound/safener

Ex. No. IIa-101=

TABLE A1 Post emergence test/greenhouse Damage Application rate Winter barley Active compound (+safener) (g of a.i./ha) (in %) propoxycarbazone-sodium 4 60 2 35 propoxycarbazone-sodium + 4 + 100 40 Ex. No. IIa-101 2 + 100 25

TABLE A2 Post emergence test/greenhouse Damage Application rate Winter barley Active compound (+safener) (g of a.i./ha) (in %) flucarbazone-sodium 8 40 flucarbazone-sodium + 8 + 100 20 Ex. No. IIa-101

TABLE A1 Post emergence test/greenhouse Damage Application rate Winter barley Safener (g of a.i./ha) (in %) Ex. No. IIa-101 100 0 30 0 

1-11. (canceled)
 12. A composition comprising an effective amount of an active compound combination comprising (a) one or more substituted arylsulphonylaminocarbonyl-triazolinones of formula (I)

 including any tautomeric forms thereof or a salt formed by a compound of formula (I) and a basic compound including any tautomeric forms thereof, in which R¹ represents hydrogen, hydroxyl, amino, or C₂-C₆-alkylideneamino; represents optionally cyano-, halogen-, or C₁-C₄-alkoxy-substituted alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkylamino, or dialkylamino having in each case up to 6 carbon atoms; represents optionally cyano-, halogen-, or C₁-C₄-alkyl-substituted cycloalkyl, cycloalkylalkyl, or cycloalkylamino having in each case 3 to 6 carbon atoms in the cycloalkyl group and, where appropriate, 1 to 4 carbon atoms in any alkyl moiety; or represents optionally cyano-, nitro-, halogen-, C₁-C₄-alkyl-, C₁-C₄-haloalkyl-, C₁-C₄-alkoxy-, or C₁-C₄-haloalkoxy-substituted phenyl or phenyl-C₁-C₄-alkyl, R² represents hydrogen, hydroxyl, mercapto, amino, cyano, or halogen; represents optionally cyano-, halogen-, or C₁-C₄-alkoxy-substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkynyl, alkenyloxy, alkynyloxy, alkenylthio, alkynylthio, alkenylamino, or alkynylamino having in each case up to 6 carbon atoms; represents optionally cyano-, halogen-, or C₁-C₄-alkyl-substituted cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylalkylthio, or cycloalkylalkylamino having in each case 3 to 6 carbon atoms in the cycloalkyl group and, where appropriate, 1 to 4 carbon atoms in any alkyl moiety; or represents optionally cyano-, nitro-, halogen-, C₁-C₄-alkyl-, C₁-C₄-haloalkyl-, C₁-C4-alkoxy-, or C₁-C₄-haloalkoxy-substituted phenyl, phenoxy, phenylthio, phenylamino, or phenyl-C₁-C₄-alkyl, R³ represents nitro, cyano, or halogen; represents optionally cyano-, halogen-, or C₁-C₄-alkoxy-substituted alkyl, alkylcarbonyl, alkoxy, alkoxycarbonyl, alkylthio, alkylsulphinyl, alkylsulphonyl, alkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, alkynyl, alkynyloxy, or alkynylthio having in each case up to 6 carbon atoms; represents optionally cyano-, halogen-, or C₁-C₄-alkyl-substituted cycloalkyl, cycloalkyloxy, cycloalkylthio, or cycloalkylamino having in each case 3 to 6 carbon atoms in the cycloalkyl groups; or represents optionally cyano-, nitro-, halogen-, C₁-C₄-alkyl-, C₁-C₄-haloalkyl-, C₁-C₄-alkoxy-, or C₁-C₄-haloalkoxy-substituted phenyl, phenoxy, phenylthio, phenylsulphinyl, phenylsulphonyl, or phenylamino, and R⁴ represents hydrogen, nitro, cyano, or halogen; represents optionally cyano-, halogen-, or C₁-C₄-alkoxy-substituted alkyl, alkylcarbonyl, alkoxy, alkoxycarbonyl, alkylthio, alkylsulphinyl, alkylsulphonyl, alkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, alkynyl, alkynyloxy, or alkynylthio having in each case up to 6 carbon atoms; represents optionally cyano-, halogen-, or C₁-C₄-alkyl-substituted cycloalkyl, cycloalkyloxy, cycloalkylthio, or cycloalkylamino having in each case 3 to 6 carbon atoms in the cycloalkyl groups; or represents optionally cyano-, nitro-, halogen-, C₁-C₄-alkyl-, C₁-C₄-haloalkyl-, C₁-C₄-alkoxy-, or C₁-C₄-haloalkoxy-substituted phenyl, phenoxy, phenylthio, phenylsulphinyl, phenylsulphonyl, or phenylamino, and (b) one or more compounds that improves crop plant compatibility selected from the group consisting of compounds of formula (II)

 in which m represents the numbers 0 to 5, n represents the numbers 0 to 4, X represents nitro, cyano, carboxyl, carbamoyl, formyl, sulfamoyl, hydroxyl, amino, or halogen; or represents optionally cyano-, halogen-, or C₁-C₄-alkoxy-substituted alkyl, alkoxy, alkoxycarbonyl, alkylthio, alkylsulphinyl, alkylsulphonyl, alkylamino, or alkylaminocarbonyl having in each case 1 to 6 carbon atoms in the alkyl groups; or represents dialkylamino, dialkylaminocarbonyl, or dialkylaminosulphonyl having in each case 1 to 6 carbon atoms in the alkyl groups, Y represents nitro, cyano, carboxyl, carbamoyl, formyl, sulfamoyl, hydroxyl, amino, or halogen; or represents optionally cyano-, halogen-, or C₁-C₄-alkoxy-substituted alkyl or alkoxy having in each case 1 to 6 carbon atoms, and Z represents one of the groups

 in which R⁵ represents hydrogen; represents optionally cyano-, halogen-, or C₁-C₄-alkoxy-substituted alkyl having 1 to 6 carbon atoms; represents optionally halogen-substituted alkenyl or alkynyl having in each case 3 to 6 carbon atoms; or represents optionally halogen- or C₁-C₄-alkyl-substituted cycloalkyl or cycloalkylalkyl having in each case 3 to 6 carbon atoms in the cycloalkyl group and, where appropriate, 1 to 4 carbon atoms in any alkyl moiety, R⁶ represents hydrogen; represents optionally cyano-, halogen-, C₁-C₄-alkoxy-, or C₁-C₄-alkylthio-substituted alkyl, alkoxy, or alkylthio having in each case 1 to 6 carbon atoms; represents optionally halogen-substituted alkenyl, alkenyloxy, alkenylthio, alkynyl, alkynyloxy, or alkynylthio having in each case up to 6 carbon atoms; represents optionally halogen- or C₁-C₄-alkyl-substituted cycloalkyl or cycloalkylalkyl having in each case 3 to 6 carbon atoms in the cycloalkyl group and, where appropriate, 1 to 4 carbon atoms in any alkyl moiety; represents optionally nitro-, cyano-, halogen-, C₁-C₄-alkyl-, C₁-C₄-haloalkyl-, C₁-C₄-alkoxy-, or C₁-C₄-haloalkoxy-substituted aryl, aryloxy, arylthio, arylalkyl, arylalkoxy, or arylalkylthio having in each case 6 or 10 carbon atoms in the aryl group and, where appropriate, 1 to 4 carbon atoms in any alkyl moiety; or represents optionally nitro-, cyano-, halogen-, C₁-C₄-alkyl-, C₁-C₄-haloalkyl-, C₁-C₄-alkoxy-, or C₁-C₄-haloalkoxy-substituted heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylalkyl, heterocyclylalkoxy, or heterocyclylalkylthio having in each case up to 10 carbon atoms, 1 to 4 nitrogen atoms and/or 1 or 2 oxygen or sulphur atoms in the heterocyclyl group and, where appropriate, 1 to 4 carbon atoms in any alkyl moiety, and R⁷ represents hydrogen; represents optionally cyano-, halogen-, or C₁-C₄-alkoxy-substituted alkyl having 1 to 6 carbon atoms; represents alkoxy having 1 to 6 carbon atoms; represents optionally halogen-substituted alkenyl or alkynyl having in each case 3 to 6 carbon atoms; represents alkenyloxy having 3 to 6 carbon atoms; represents optionally halogen- or C₁-C₄-alkyl-substituted cycloalkyl or cycloalkylalkyl having 3 to 6 carbon atoms in the cycloalkyl group and, where appropriate, 1 to 4 carbon atoms in any alkyl moiety; or represents optionally nitro-, cyano-, halogen-, C₁-C₄-alkyl-, C₁-C₄-haloalkyl-, C₁-C₄-alkoxy-, or C₁-C₄-haloalkoxy-substituted aryl or arylalkyl having in each case 6 or 10 carbon atoms in the aryl group and, where appropriate, 1 to 4 carbon atoms in any alkyl moiety; or R⁷ together with R⁵ represents optionally C₁-C₄-alkyl-substituted alkanediyl having 2 to 6 carbon atoms or oxaalkanediyl having 2 to 5 carbon atoms.
 13. A composition according to claim 12 in which R¹ represents hydrogen, amino, propylideneamino, or butylideneamino; represents optionally cyano-, fluorine-, chlorine-, methoxy-, or ethoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s-, or t-butyl, ethenyl, propenyl, butenyl, ethynyl, propynyl, butynyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s-, or t-butoxy, propenyloxy, butenyloxy, methylamino, ethylamino, n- or i-propylamino, n-, i-, s-, or t-butylamino, dimethylamino, or diethylamino; represents optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, or n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl, cyclopropylamino, cyclobutylamino, cyclopentylamino, or cyclohexylamino; or represents optionally cyano-, nitro-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s-, or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, difluoromethoxy-, or trifluoromethoxy-substituted phenyl or benzyl, R² represents hydrogen, hydroxyl, mercapto, amino, cyano, fluorine, chlorine, or bromine; represents optionally cyano-, fluorine-, chlorine-, methoxy-, or ethoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s-, or t-butyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s-, or t-butoxy, methylthio, ethylthio, n- or i-propylthio, n-, i-, s-, or t-butylthio, methylamino, ethylamino, n- or i-propylamino, n-, i-, s-, or t-butylamino, dimethylamino, diethylamino, ethenyl, propenyl, butenyl, ethynyl, propynyl, butynyl, propenyloxy, butenyloxy, propynyloxy, butynyloxy, propenylthio, butenylthio, propynylthio, butynylthio, propenylamino, butenylamino, propynylamino, or butynylamino; represents optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, or n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropyloxy, cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, cyclopropylthio, cyclobutylthio, cyclopentylthio, cyclohexylthio, cyclopropylamino, cyclobutylamino, cyclopentylamino, cyclohexylamino, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl, cyclopropylmethoxy, cyclobutylmethoxy, cyclopentylmethoxy, cyclohexylmethoxy, cyclopropylmethylthio, cyclobutylmethylthio, cyclopentylmethylthio, cyclohexylmethylthio, cyclopropylmethylamino, cyclobutylmethylamino, cyclopentylmethylamino, or cyclohexylmethylamino; or represents optionally cyano-, nitro-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s-, or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, difluoromethoxy-, or trifluoromethoxy-substituted phenyl, phenoxy, phenylthio, phenylamino, or benzyl, R³ represents nitro, cyano, fluorine, chlorine, or bromine; represents optionally cyano-, fluorine-, chlorine-, methoxy-, or ethoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s-, or t-butyl, acetyl, propionyl, n- or i-butyroyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s-, or t-butoxy, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, methylthio, ethylthio, n- or i-propylthio, n-, i-, s-, or t-butylthio, methylsulphinyl, ethylsulphinyl, n- or i-propylsulphinyl, methylsulphonyl, ethylsulphonyl, n- or i-propylsulphonyl, methylamino, ethylamino, n- or i-propylamino, n-, i-, s-, or t-butylamino, ethenyl, propenyl, butenyl, propenyloxy, butenyloxy, propenylthio, butenylthio, propenylamino, butenylamino, ethynyl, propynyl, butynyl, propynyloxy, butynyloxy, propynylthio, or butynylthio; represents optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, or n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropyloxy, cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, cyclopropylthio, cyclobutylthio, cyclopentylthio, cyclohexylthio, cyclopropylamino, cyclobutylamino, cyclopentylamino, or cyclohexylamino; or represents optionally cyano-, nitro-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s-, or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-, n-, i-, s-, or t-butoxy-, difluoromethoxy-, or trifluoromethoxy-substituted phenyl, phenoxy, phenylthio, phenylsulphinyl, phenylsulphonyl, or phenylamino, and R⁴ represents hydrogen, nitro, cyano, fluorine, chlorine, or bromine; represents optionally cyano-, fluorine-, chlorine-, methoxy-, or ethoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s-, or t-butyl, acetyl, propionyl, n- or i-butyroyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s-, or t-butoxy, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, methylthio, ethylthio, n- or i-propylthio, n-, i-, s-, or t-butylthio, methylsulphinyl, ethylsulphinyl, n- or i-propylsulphinyl, methylsulphonyl, ethylsulphonyl, n- or i-propylsulphonyl, methylamino, ethylamino, n- or i-propylamino, n-, i-, s-, or t-butylamino, ethenyl, propenyl, butenyl, propenyloxy, butenyloxy, propenylthio, butenylthio, propenylamino, butenylamino, ethynyl, propynyl, butynyl, propynyloxy, butynyloxy, propynylthio, or butynylthio; represents optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, or n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropyloxy, cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, cyclopropylthio, cyclobutylthio, cyclopentylthio, cyclohexylthio, cyclopropylamino, cyclobutylamino, cyclopentylamino, or cyclohexylamino; or represents optionally cyano-, nitro-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-, n-, i-, s-, or t-butoxy-, difluoromethoxy-, or trifluoromethoxy-substituted phenyl, phenoxy, phenylthio, phenylsulphinyl, phenylsulphonyl, or phenylamino.
 14. A composition according to claim 12 in which R¹ represents hydrogen, or amino; represents optionally fluorine-, chlorine-, methoxy-, or ethoxy-substituted methyl, ethyl, ethenyl, propenyl, ethynyl, propynyl, methoxy, ethoxy, n- or i-propoxy, methylamino, or ethylamino; represents dimethylamino; or represents optionally fluorine-, chlorine-, or methyl-substituted cyclopropyl, R² represents hydrogen, chlorine, or bromine; represents optionally fluorine-, chlorine-, methoxy-, or ethoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, or s-butyl, methoxy, ethoxy, n- or i-propoxy, methylthio, ethylthio, n- or i-propylthio, methylamino, ethylamino, n- or i-propylamino, dimethylamino, diethylamino, ethenyl, propenyl, butenyl, ethynyl, propynyl, butynyl, propenyloxy, butenyloxy, propynyloxy, butynyloxy, propenylthio, butenylthio, propynylthio, butynylthio, propenylamino, butenylamino, propynylamino, or butynylamino; or represents optionally fluorine-, chlorine-, or methyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropyloxy, cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, cyclopropylthio, cyclobutylthio, cyclopentylthio, cyclohexylthio, cyclopropylamino, cyclobutylamino, cyclopentylamino, cyclohexylamino, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl, cyclopropylmethoxy, cyclobutylmethoxy, cyclopentylmethoxy, cyclohexylmethoxy, cyclopropylmethylthio, cyclobutylmethylthio, cyclopentylmethylthio, cyclohexylmethylthio, cyclopropylmethylamino, cyclobutylmethylamino, cyclopentylmethylamino, or cyclohexylmethylamino, R³ represents nitro, cyano, fluorine, chlorine, or bromine; represents optionally fluorine-, chlorine-, methoxy-, or ethoxy-substituted methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, methylthio, ethylthio, n- or i-propylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl, or ethylsulphonyl; represents optionally fluorine-, chlorine-, or methyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropyloxy, cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, cyclopropylthio, cyclobutylthio, cyclopentylthio, or cyclohexylthio; or represents optionally cyano-, nitro-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s-, or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-, difluoromethoxy-, or trifluoromethoxy-substituted phenyl, phenoxy, phenylthio, phenylsulphinyl, or phenylsulphonyl, and R⁴ represents hydrogen, nitro, cyano, fluorine, chlorine, or bromine; or represents optionally fluorine-, chlorine-, methoxy-, or ethoxy-substituted methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, methylthio, ethylthio, n- or i-propylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl, or ethylsulphonyl.
 15. A composition according to claim 12 in which R¹ represents hydrogen; represents optionally fluorine-, chlorine-, methoxy-, or ethoxy-substituted methyl, ethyl, ethenyl, methoxy, ethoxy, methylamino, or ethylamino; represents dimethylamino; or represents optionally fluorine-, chlorine-, or methyl-substituted cyclopropyl, R² represents hydrogen, chlorine, or bromine; represents optionally fluorine-, chlorine-, methoxy-, or ethoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, or s-butyl, methoxy, ethoxy, n- or i-propoxy, methylthio, ethylthio, n- or i-propylthio, methylamino, ethylamino, n- or i-propylamino, dimethylamino, diethylamino, ethenyl, propenyl, butenyl, ethynyl, propynyl, butynyl, propenyloxy, butenyloxy, propynyloxy, butynyloxy, propenylthio, butenylthio, propynylthio, or butynylthio, or represents optionally fluorine-, chlorine-, or methyl-substituted cyclopropyl, cyclopropyloxy, cyclopropylthio, cyclopropylmethyl, cyclopropylmethoxy, or cyclopropylmethylthio, R³ represents nitro, cyano, fluorine, chlorine, or bromine; represents optionally fluorine-, chlorine-, methoxy-, or ethoxy-substituted methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, methylthio, ethylthio, n- or i-propylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl, or ethylsulphonyl; or represents optionally cyano-, nitro-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, trifluoromethyl-, methoxy-, ethoxy-, difluoromethoxy-, or trifluoromethoxy-substituted phenyl or phenoxy, and R⁴ represents hydrogen, nitro, cyano, fluorine, chlorine, or bromine; or represents optionally fluorine-, chlorine-, methoxy-, or ethoxy-substituted methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, methylthio, ethylthio, n- or i-propylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl, or ethylsulphonyl.
 16. A composition according to claim 12 in which m represents the number 0, 1, 2, 3, or 4, n represents the number 0, 1, 2, or 3, X represents nitro, cyano, carboxyl, carbamoyl, formyl, sulfamoyl, hydroxy, amino, or halogen; represents optionally cyano-, halogen-, methoxy-, ethoxy-, or n- or i-propoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s-, or t-butyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s-, or t-butoxy, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, n-, i-, s-, or t-butoxycarbonyl, methylthio, ethylthio, n- or i-propylthio, n-, i-, s-, or t-butylthio, methylsulphinyl, ethylsulphinyl, n- or i-propylsulphinyl, methylsulphonyl, ethylsulphonyl, methylamino, ethylamino, n- or i-propylamino, n-, i-, s-, or t-butylamino, methylaminocarbonyl, ethylaminocarbonyl, or n- or i-propylaminocarbonyl; or represents dimethylamino, diethylamino, dimethylaminocarbonyl, or dimethylaminosulphonyl, Y represents nitro, cyano, carboxyl, carbamoyl, formyl, sulphamoyl, hydroxyl, amino, or halogen; or represents optionally cyano-, halogen-, methoxy-, ethoxy-, or n- or i-propoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s-, or t-butyl, methoxy, ethoxy, n- or i-propoxy, or n-, i-, s-, or t-butoxy, and Z represents one of the groups

 in which R⁵ represents hydrogen; represents optionally cyano-, halogen-, methoxy-, ethoxy-, n- or i-propoxy-, or n-, i-, s-, or t-butoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s-, or t-butyl, n-, i-, s-, or t-pentyl, or neo-pentyl; represents optionally halogen-substituted propenyl, butenyl, pentenyl, propynyl, butynyl, or pentynyl; or represents optionally halogen-, methyl-, ethyl-, or n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, or cyclohexylmethyl, R⁶ represents hydrogen; represents optionally cyano-, halogen-, methoxy-, ethoxy-, n- or i-propoxy-, n-, i-, s-, or t-butoxy-, methylthio-, ethylthio-, n- or i-propylthio-, or n-, i-, s-, or t-butylthio-substituted methyl, ethyl, n- or i-propyl, n-, i-, s-, or t-butyl, n-, i-, s-, or t-pentyl, neo-pentyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s-, or t-butoxy, methylthio, ethylthio, n- or i-propylthio, or n-, i-, s-, or t-butylthio; represents optionally halogen-substituted propenyl, butenyl, pentenyl, propenyloxy, butenyloxy, pentenyloxy, propenylthio, butenylthio, pentenylthio, propynyl, butynyl, pentynyl, propynyloxy, butynyloxy, pentynyloxy, propynylthio, butynylthio, or pentynylthio; represents optionally halogen-, methyl-, ethyl-, or n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, or cyclohexylmethyl; represents optionally nitro-, cyano-, halogen-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s-, or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-, difluoromethoxy-, or trifluoromethoxy-substituted phenyl, naphthyl, phenoxy, phenylthio, benzyl, phenylethyl, phenylmethoxy, phenylethoxy, or phenylmethylthio; or represents optionally nitro-, cyano-, halogen-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s-, or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-, difluoromethoxy-, or trifluoromethoxy-substituted heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylmethyl, heterocyclylmethoxy, or heterocyclylmethylthio, where each heterocyclyl group is selected from the group consisting of furyl, thienyl, pyrazolyl, pyridinyl, and pyrimidinyl, R⁷ represents hydrogen; represents optionally cyano-, halogen-, methoxy-, ethoxy-, n- or i-propoxy-, or n-, i-, s-, or t-butoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s-, or t-butyl, n-, i-, s-, or t-pentyl, or neo-pentyl; represents methoxy, ethoxy, n- or i-propoxy, or n-, i-, s-, or t-butoxy; represents optionally halogen-substituted propenyl, butenyl, pentenyl, propynyl, butynyl, or pentynyl; represents propenyloxy, butenyloxy, or pentenyloxy; represents optionally halogen-, methyl-, ethyl-, or n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, or cyclohexylmethyl; or represents optionally nitro-, cyano-, halogen-, methyl-, ethyl-, n- or i-propyl, n-, i-, s-, or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-, difluoromethoxy-, or trifluoromethoxy-substituted phenyl, naphthyl, benzyl, or phenylethyl; or R⁷ together with R⁵ represents optionally methyl- or ethyl-substituted butane-1,4-diyl (tetramethylene), 1-oxabutan-1,4-diyl, pentane-1,5-diyl, 1-oxapentane-1,5-diyl, or 3-oxapentane-1,5-diyl.
 17. A composition according to claim 12 in which m represents the number 1 or 2, n represents the number 0, X represents nitro, cyano, fluorine, chlorine, or bromine; represents optionally fluorine-, chlorine-, methoxy-, or ethoxy-substituted methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, methylthio, ethylthio, n- or i-propylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl, ethylsulphonyl, methylamino, ethylamino, n- or i-propylamino, methylaminocarbonyl, ethylaminocarbonyl, or n- or i-propylaminocarbonyl; or represents dimethylamino, dimethylaminocarbonyl, or dimethylaminosulphonyl, and Z represents one of the groups

 in which R⁵ represents hydrogen; represents optionally cyano-, fluorine-, chlorine-, methoxy-, ethoxy-, or n- or i-propoxy-substituted methyl, ethyl, n- or i-propyl, or n- or i-butyl; represents optionally fluorine- and/or chlorine-substituted propenyl, butenyl, propynyl, or butynyl; or represents optionally fluorine-, chlorine-, methyl-, or ethyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, or cyclohexylmethyl, R⁶ represents hydrogen; represents optionally cyano-, fluorine-, chlorine-, bromine-, methoxy-, ethoxy-, n- or i-propoxy-, methylthio-, ethylthio-, or n- or i-propylthio-substituted methyl, ethyl, n- or i-propyl, n-, i-, s-, or t-butyl, n-, i-, s-, or t-pentyl, neo-pentyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s-, or t-butoxy, methylthio, ethylthio, n- or i-propylthio, or n-, i-, s-, or t-butylthio; represents optionally fluorine- and/or chlorine-substituted propenyl, butenyl, pentenyl, propenyloxy, butenyloxy, pentenyloxy, propenylthio, butenylthio, pentenylthio, propynyl, butynyl, pentynyl, propynyloxy, butynyloxy, pentynyloxy, propynylthio, butynylthio, or pentynylthio; represents optionally fluorine-, chlorine-, methyl-, or ethyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, or cyclohexylmethyl; represents optionally nitro-, cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s-, or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-, difluoromethoxy-, or trifluoromethoxy-substituted phenyl, phenoxy, phenylthio, benzyl, phenylethyl, phenylmethoxy, phenylethoxy, or phenylmethylthio; or represents optionally nitro-, cyano-, halogen-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s-, or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-, difluoromethoxy-, or trifluoromethoxy-substituted heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylmethyl, heterocyclylmethoxy, or heterocyclylmethylthio, where each heterocyclyl group is selected from the group consisting of furyl, thienyl, pyrazolyl, pyridinyl, and pyrimidinyl, and R⁷ represents hydrogen; represents optionally cyano-, fluorine-, chlorine-, methoxy-, ethoxy-, or n- or i-propoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s-, or t-butyl, n-, i-, s-, or t-pentyl, or neo-pentyl; represents methoxy, ethoxy, n- or i-propoxy, or n-, i-, s-, or t-butoxy, represents optionally fluorine- and/or chlorine-substituted propenyl, butenyl, pentenyl, propynyl, butynyl, or pentynyl; represents propenyloxy, butenyloxy, or pentenyloxy; represents optionally fluorine-, chlorine-, methyl-, or ethyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, or cyclohexylmethyl; or represents optionally nitro-, cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s-, or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-, difluoromethoxy-, or trifluoromethoxy-substituted phenyl, benzyl, or phenylethyl; or R⁷ together with R⁵ represents optionally methyl- or ethyl-substituted butane-1,4-diyl (tetramethylene), 1-oxabutane-1,4-diyl, pentane-1,5-diyl, 1-oxapentane-1,5-diyl, or 3-oxapentane-1,5-diyl.
 18. A composition according to claim 12 in which the compound of formula (I) is one or more compounds selected from the compounds 2-(2-methoxycarbonyl-phenylsulphonylaminocarbonyl)-4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazol-3-one (propoxycarbazone), 2-(2-trifluoromethoxy-phenylsulphonylaminocarbonyl)-4-methyl-5-methoxy-2,4-dihydro-3H-1,2,4-triazol-3-one (flucarbazone), and the corresponding sodium salts (propoxycarbazone-sodium and flucarbazone-sodium).
 19. A composition according to claim 12 in which the compound of the formula (II) is 2-methoxy-N-[4-(2-methoxybenzoylsulphamoyl)phenyl]acetamide.
 20. A method for controlling undesirable plants comprising allowing an effective amount of a composition according to claim 12 to act on undesirable plants and/or their habitat.
 21. A process for preparing a herbicidal composition comprising mixing a composition according to claim 12 with one or more surfactants and/or extenders. 